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Acidic Zeolite-Catalyzed Reaction of 2,4-Diaryl-1,1,1-trifluorobut-3-yn-2-ols with Benzene. A New Synthesis of 1,3-Diaryl-1-trifluoromethylindenes. / Nursahedova, S. K.; Zerov, A. V.; Vasilyev, A. V.
в: Russian Journal of Organic Chemistry, Том 54, № 12, 01.12.2018, стр. 1764-1771.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Acidic Zeolite-Catalyzed Reaction of 2,4-Diaryl-1,1,1-trifluorobut-3-yn-2-ols with Benzene. A New Synthesis of 1,3-Diaryl-1-trifluoromethylindenes
AU - Nursahedova, S. K.
AU - Zerov, A. V.
AU - Vasilyev, A. V.
PY - 2018/12/1
Y1 - 2018/12/1
N2 - Reactions of 2,4-diaryl-1,1,1-trifluorobut-3-yn-2-ols with benzene in the presence of HUSY acidic zeolite (CBV-720) at 100°C in 1 h (glass high-pressure reactor) led to the formation of 1,3-diaryl-1-trifluoromethylindenes in 39–92% yield. A probable reaction mechanism was proposed, which involves formation of the corresponding trifluoromethyl-substituted propargyl cations.
AB - Reactions of 2,4-diaryl-1,1,1-trifluorobut-3-yn-2-ols with benzene in the presence of HUSY acidic zeolite (CBV-720) at 100°C in 1 h (glass high-pressure reactor) led to the formation of 1,3-diaryl-1-trifluoromethylindenes in 39–92% yield. A probable reaction mechanism was proposed, which involves formation of the corresponding trifluoromethyl-substituted propargyl cations.
UR - http://www.scopus.com/inward/record.url?scp=85063135643&partnerID=8YFLogxK
U2 - 10.1134/S1070428018120047
DO - 10.1134/S1070428018120047
M3 - Article
AN - SCOPUS:85063135643
VL - 54
SP - 1764
EP - 1771
JO - Russian Journal of Organic Chemistry
JF - Russian Journal of Organic Chemistry
SN - 1070-4280
IS - 12
ER -
ID: 44001934