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Acidic Zeolite-Catalyzed Reaction of 2,4-Diaryl-1,1,1-trifluorobut-3-yn-2-ols with Benzene. A New Synthesis of 1,3-Diaryl-1-trifluoromethylindenes. / Nursahedova, S. K.; Zerov, A. V.; Vasilyev, A. V.

In: Russian Journal of Organic Chemistry, Vol. 54, No. 12, 01.12.2018, p. 1764-1771.

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@article{828bf722c8634959936d4136fb90762f,
title = "Acidic Zeolite-Catalyzed Reaction of 2,4-Diaryl-1,1,1-trifluorobut-3-yn-2-ols with Benzene. A New Synthesis of 1,3-Diaryl-1-trifluoromethylindenes",
abstract = "Reactions of 2,4-diaryl-1,1,1-trifluorobut-3-yn-2-ols with benzene in the presence of HUSY acidic zeolite (CBV-720) at 100°C in 1 h (glass high-pressure reactor) led to the formation of 1,3-diaryl-1-trifluoromethylindenes in 39–92% yield. A probable reaction mechanism was proposed, which involves formation of the corresponding trifluoromethyl-substituted propargyl cations.",
author = "Nursahedova, {S. K.} and Zerov, {A. V.} and Vasilyev, {A. V.}",
year = "2018",
month = dec,
day = "1",
doi = "10.1134/S1070428018120047",
language = "English",
volume = "54",
pages = "1764--1771",
journal = "Russian Journal of Organic Chemistry",
issn = "1070-4280",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "12",

}

RIS

TY - JOUR

T1 - Acidic Zeolite-Catalyzed Reaction of 2,4-Diaryl-1,1,1-trifluorobut-3-yn-2-ols with Benzene. A New Synthesis of 1,3-Diaryl-1-trifluoromethylindenes

AU - Nursahedova, S. K.

AU - Zerov, A. V.

AU - Vasilyev, A. V.

PY - 2018/12/1

Y1 - 2018/12/1

N2 - Reactions of 2,4-diaryl-1,1,1-trifluorobut-3-yn-2-ols with benzene in the presence of HUSY acidic zeolite (CBV-720) at 100°C in 1 h (glass high-pressure reactor) led to the formation of 1,3-diaryl-1-trifluoromethylindenes in 39–92% yield. A probable reaction mechanism was proposed, which involves formation of the corresponding trifluoromethyl-substituted propargyl cations.

AB - Reactions of 2,4-diaryl-1,1,1-trifluorobut-3-yn-2-ols with benzene in the presence of HUSY acidic zeolite (CBV-720) at 100°C in 1 h (glass high-pressure reactor) led to the formation of 1,3-diaryl-1-trifluoromethylindenes in 39–92% yield. A probable reaction mechanism was proposed, which involves formation of the corresponding trifluoromethyl-substituted propargyl cations.

UR - http://www.scopus.com/inward/record.url?scp=85063135643&partnerID=8YFLogxK

U2 - 10.1134/S1070428018120047

DO - 10.1134/S1070428018120047

M3 - Article

AN - SCOPUS:85063135643

VL - 54

SP - 1764

EP - 1771

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 12

ER -

ID: 44001934