Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
A Fresh Look on the Nature of the Dual-Band Emission of the Octahedral Copper Iodide Clusters – Promising Ratiometric Luminescent Thermometers. / Shamsieva, Alina V.; Kolesnikov, Ilya E.; Strelnik, Igor D.; Gerasimova, Tatiana P.; Kalinichev, Alexey A.; Katsyuba, Sergey A.; Musina, Elvira; Lahderanta, Erkki; Karasik, Andrey A.; Sinyashin, Oleg G.
в: Journal of Physical Chemistry C, Том 123, № 42, 2019, стр. 25863-25870.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - A Fresh Look on the Nature of the Dual-Band Emission of the Octahedral Copper Iodide Clusters – Promising Ratiometric Luminescent Thermometers
AU - Shamsieva, Alina V.
AU - Kolesnikov, Ilya E.
AU - Strelnik, Igor D.
AU - Gerasimova, Tatiana P.
AU - Kalinichev, Alexey A.
AU - Katsyuba, Sergey A.
AU - Musina, Elvira
AU - Lahderanta, Erkki
AU - Karasik, Andrey A.
AU - Sinyashin, Oleg G.
PY - 2019
Y1 - 2019
N2 - For the first time, the 3(X + M)LCT origin of both the lowest excited triplet states of dual-emissive tetranuclear copper(I)-iodide complexes with the octahedral Cu4I4 core has been revealed using quantum chemical computations in contrast to the conventional assignment of the lowest-energy emission to the 3CC state. The unusual thermochromic behavior shown for dual emission from these states of Cu4I4 clusters stabilized by P,N-ligands allows optical ratiometric thermal sensing in a broad temperature range.
AB - For the first time, the 3(X + M)LCT origin of both the lowest excited triplet states of dual-emissive tetranuclear copper(I)-iodide complexes with the octahedral Cu4I4 core has been revealed using quantum chemical computations in contrast to the conventional assignment of the lowest-energy emission to the 3CC state. The unusual thermochromic behavior shown for dual emission from these states of Cu4I4 clusters stabilized by P,N-ligands allows optical ratiometric thermal sensing in a broad temperature range.
UR - https://pubs.acs.org/doi/abs/10.1021/acs.jpcc.9b07603
M3 - Article
VL - 123
SP - 25863
EP - 25870
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
SN - 1932-7447
IS - 42
ER -
ID: 49772782