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A Fresh Look on the Nature of the Dual-Band Emission of the Octahedral Copper Iodide Clusters – Promising Ratiometric Luminescent Thermometers. / Shamsieva, Alina V.; Kolesnikov, Ilya E.; Strelnik, Igor D.; Gerasimova, Tatiana P.; Kalinichev, Alexey A.; Katsyuba, Sergey A.; Musina, Elvira; Lahderanta, Erkki; Karasik, Andrey A.; Sinyashin, Oleg G.
In:
Journal of Physical Chemistry C, Vol. 123, No. 42, 2019, p. 25863-25870.
Research output: Contribution to journal › Article › peer-review
Harvard
Shamsieva, AV
, Kolesnikov, IE, Strelnik, ID, Gerasimova, TP, Kalinichev, AA, Katsyuba, SA, Musina, E, Lahderanta, E, Karasik, AA & Sinyashin, OG 2019, '
A Fresh Look on the Nature of the Dual-Band Emission of the Octahedral Copper Iodide Clusters – Promising Ratiometric Luminescent Thermometers',
Journal of Physical Chemistry C, vol. 123, no. 42, pp. 25863-25870.
APA
Shamsieva, A. V.
, Kolesnikov, I. E., Strelnik, I. D., Gerasimova, T. P., Kalinichev, A. A., Katsyuba, S. A., Musina, E., Lahderanta, E., Karasik, A. A., & Sinyashin, O. G. (2019).
A Fresh Look on the Nature of the Dual-Band Emission of the Octahedral Copper Iodide Clusters – Promising Ratiometric Luminescent Thermometers.
Journal of Physical Chemistry C,
123(42), 25863-25870.
Vancouver
Author
Shamsieva, Alina V.
; Kolesnikov, Ilya E. ; Strelnik, Igor D. ; Gerasimova, Tatiana P. ; Kalinichev, Alexey A. ; Katsyuba, Sergey A. ; Musina, Elvira ; Lahderanta, Erkki ; Karasik, Andrey A. ; Sinyashin, Oleg G. /
A Fresh Look on the Nature of the Dual-Band Emission of the Octahedral Copper Iodide Clusters – Promising Ratiometric Luminescent Thermometers. In:
Journal of Physical Chemistry C. 2019 ; Vol. 123, No. 42. pp. 25863-25870.
BibTeX
@article{cf24ab34f40b4e28ae287fccdaaf498b,
title = "A Fresh Look on the Nature of the Dual-Band Emission of the Octahedral Copper Iodide Clusters – Promising Ratiometric Luminescent Thermometers",
abstract = "For the first time, the 3(X + M)LCT origin of both the lowest excited triplet states of dual-emissive tetranuclear copper(I)-iodide complexes with the octahedral Cu4I4 core has been revealed using quantum chemical computations in contrast to the conventional assignment of the lowest-energy emission to the 3CC state. The unusual thermochromic behavior shown for dual emission from these states of Cu4I4 clusters stabilized by P,N-ligands allows optical ratiometric thermal sensing in a broad temperature range.",
author = "Shamsieva, {Alina V.} and Kolesnikov, {Ilya E.} and Strelnik, {Igor D.} and Gerasimova, {Tatiana P.} and Kalinichev, {Alexey A.} and Katsyuba, {Sergey A.} and Elvira Musina and Erkki Lahderanta and Karasik, {Andrey A.} and Sinyashin, {Oleg G.}",
year = "2019",
language = "English",
volume = "123",
pages = "25863--25870",
journal = "Journal of Physical Chemistry C",
issn = "1932-7447",
publisher = "American Chemical Society",
number = "42",
}
RIS
TY - JOUR
T1 - A Fresh Look on the Nature of the Dual-Band Emission of the Octahedral Copper Iodide Clusters – Promising Ratiometric Luminescent Thermometers
AU - Shamsieva, Alina V.
AU - Kolesnikov, Ilya E.
AU - Strelnik, Igor D.
AU - Gerasimova, Tatiana P.
AU - Kalinichev, Alexey A.
AU - Katsyuba, Sergey A.
AU - Musina, Elvira
AU - Lahderanta, Erkki
AU - Karasik, Andrey A.
AU - Sinyashin, Oleg G.
PY - 2019
Y1 - 2019
N2 - For the first time, the 3(X + M)LCT origin of both the lowest excited triplet states of dual-emissive tetranuclear copper(I)-iodide complexes with the octahedral Cu4I4 core has been revealed using quantum chemical computations in contrast to the conventional assignment of the lowest-energy emission to the 3CC state. The unusual thermochromic behavior shown for dual emission from these states of Cu4I4 clusters stabilized by P,N-ligands allows optical ratiometric thermal sensing in a broad temperature range.
AB - For the first time, the 3(X + M)LCT origin of both the lowest excited triplet states of dual-emissive tetranuclear copper(I)-iodide complexes with the octahedral Cu4I4 core has been revealed using quantum chemical computations in contrast to the conventional assignment of the lowest-energy emission to the 3CC state. The unusual thermochromic behavior shown for dual emission from these states of Cu4I4 clusters stabilized by P,N-ligands allows optical ratiometric thermal sensing in a broad temperature range.
UR - https://pubs.acs.org/doi/abs/10.1021/acs.jpcc.9b07603
M3 - Article
VL - 123
SP - 25863
EP - 25870
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
SN - 1932-7447
IS - 42
ER -
