“2+1” Rhenium and Technetium Tricarbonyl Complexes with N,N′-Bidentate Ligands and Methyl 11-Isocyanoundecanoate

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“2+1” Rhenium and Technetium Tricarbonyl Complexes with N,N′-Bidentate Ligands and Methyl 11-Isocyanoundecanoate. / Мирославов, Александр Евгеньевич ; Сахоненкова, Анна Павловна; Тюпина, Маргарита Юрьевна; Sidorenko, G. V.

в: Russian Journal of General Chemistry, Том 93, № 2, 01.02.2023, стр. 327–331.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{921ba4a6f1d249cabacdd068431b5ac4,

title = "“2+1” Rhenium and Technetium Tricarbonyl Complexes with N,N′-Bidentate Ligands and Methyl 11-Isocyanoundecanoate",

abstract = "Abstract: “2+1” tricarbonyl compexes [M(CO)3(N^N)CN(CH2)10COOMe]ClO4, where M = Tc or Re, N^N = 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [M(CO)3(N^N)(MeOH)]ClO4 with methyl 11-isocyanoundecanoate in methanol. The complexes were isolated and characterized by IR and 1H NMR spectroscopy and by elemental analysis. The resistance of the “2+1” tricarbonyl complexes obtained to transchelation with histidine was evaluated.",

keywords = "bipyridine, methyl 11-undecanoate, phenanthroline, rhenium, technetium, tricarbonyl complexes",

author = "Мирославов, {Александр Евгеньевич} and Сахоненкова, {Анна Павловна} and Тюпина, {Маргарита Юрьевна} and Sidorenko, {G. V.}",

year = "2023",

month = feb,

day = "1",

doi = "10.1134/S1070363223020135",

language = "English",

volume = "93",

pages = "327–331",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "2",

}

RIS

TY - JOUR

T1 - “2+1” Rhenium and Technetium Tricarbonyl Complexes with N,N′-Bidentate Ligands and Methyl 11-Isocyanoundecanoate

AU - Мирославов, Александр Евгеньевич

AU - Сахоненкова, Анна Павловна

AU - Тюпина, Маргарита Юрьевна

AU - Sidorenko, G. V.

PY - 2023/2/1

Y1 - 2023/2/1

N2 - Abstract: “2+1” tricarbonyl compexes [M(CO)3(N^N)CN(CH2)10COOMe]ClO4, where M = Tc or Re, N^N = 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [M(CO)3(N^N)(MeOH)]ClO4 with methyl 11-isocyanoundecanoate in methanol. The complexes were isolated and characterized by IR and 1H NMR spectroscopy and by elemental analysis. The resistance of the “2+1” tricarbonyl complexes obtained to transchelation with histidine was evaluated.

AB - Abstract: “2+1” tricarbonyl compexes [M(CO)3(N^N)CN(CH2)10COOMe]ClO4, where M = Tc or Re, N^N = 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [M(CO)3(N^N)(MeOH)]ClO4 with methyl 11-isocyanoundecanoate in methanol. The complexes were isolated and characterized by IR and 1H NMR spectroscopy and by elemental analysis. The resistance of the “2+1” tricarbonyl complexes obtained to transchelation with histidine was evaluated.

KW - bipyridine

KW - methyl 11-undecanoate

KW - phenanthroline

KW - rhenium

KW - technetium

KW - tricarbonyl complexes

UR - https://www.mendeley.com/catalogue/cec56a00-ce12-3f33-864a-813f6c405bf2/

U2 - 10.1134/S1070363223020135

DO - 10.1134/S1070363223020135

M3 - Article

VL - 93

SP - 327

EP - 331

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 2

ER -

ID: 114015376