Research output: Contribution to journal › Article › peer-review
“2+1” Rhenium and Technetium Tricarbonyl Complexes with N,N′-Bidentate Ligands and Methyl 11-Isocyanoundecanoate. / Мирославов, Александр Евгеньевич; Сахоненкова, Анна Павловна; Тюпина, Маргарита Юрьевна; Sidorenko, G. V.
In: Russian Journal of General Chemistry, Vol. 93, No. 2, 01.02.2023, p. 327–331.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - “2+1” Rhenium and Technetium Tricarbonyl Complexes with N,N′-Bidentate Ligands and Methyl 11-Isocyanoundecanoate
AU - Мирославов, Александр Евгеньевич
AU - Сахоненкова, Анна Павловна
AU - Тюпина, Маргарита Юрьевна
AU - Sidorenko, G. V.
PY - 2023/2/1
Y1 - 2023/2/1
N2 - Abstract: “2+1” tricarbonyl compexes [M(CO)3(N^N)CN(CH2)10COOMe]ClO4, where M = Tc or Re, N^N = 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [M(CO)3(N^N)(MeOH)]ClO4 with methyl 11-isocyanoundecanoate in methanol. The complexes were isolated and characterized by IR and 1H NMR spectroscopy and by elemental analysis. The resistance of the “2+1” tricarbonyl complexes obtained to transchelation with histidine was evaluated.
AB - Abstract: “2+1” tricarbonyl compexes [M(CO)3(N^N)CN(CH2)10COOMe]ClO4, where M = Tc or Re, N^N = 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [M(CO)3(N^N)(MeOH)]ClO4 with methyl 11-isocyanoundecanoate in methanol. The complexes were isolated and characterized by IR and 1H NMR spectroscopy and by elemental analysis. The resistance of the “2+1” tricarbonyl complexes obtained to transchelation with histidine was evaluated.
KW - bipyridine
KW - methyl 11-undecanoate
KW - phenanthroline
KW - rhenium
KW - technetium
KW - tricarbonyl complexes
UR - https://www.mendeley.com/catalogue/cec56a00-ce12-3f33-864a-813f6c405bf2/
U2 - 10.1134/S1070363223020135
DO - 10.1134/S1070363223020135
M3 - Article
VL - 93
SP - 327
EP - 331
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 2
ER -
ID: 114015376