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“2+1” Rhenium and Technetium Tricarbonyl Complexes with N,N′-Bidentate Ligands and Methyl 11-Isocyanoundecanoate. / Мирославов, Александр Евгеньевич; Сахоненкова, Анна Павловна; Тюпина, Маргарита Юрьевна; Sidorenko, G. V.

In: Russian Journal of General Chemistry, Vol. 93, No. 2, 01.02.2023, p. 327–331.

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@article{921ba4a6f1d249cabacdd068431b5ac4,
title = "“2+1” Rhenium and Technetium Tricarbonyl Complexes with N,N′-Bidentate Ligands and Methyl 11-Isocyanoundecanoate",
abstract = "Abstract: “2+1” tricarbonyl compexes [M(CO)3(N^N)CN(CH2)10COOMe]ClO4, where M = Tc or Re, N^N = 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [M(CO)3(N^N)(MeOH)]ClO4 with methyl 11-isocyanoundecanoate in methanol. The complexes were isolated and characterized by IR and 1H NMR spectroscopy and by elemental analysis. The resistance of the “2+1” tricarbonyl complexes obtained to transchelation with histidine was evaluated.",
keywords = "bipyridine, methyl 11-undecanoate, phenanthroline, rhenium, technetium, tricarbonyl complexes",
author = "Мирославов, {Александр Евгеньевич} and Сахоненкова, {Анна Павловна} and Тюпина, {Маргарита Юрьевна} and Sidorenko, {G. V.}",
year = "2023",
month = feb,
day = "1",
doi = "10.1134/S1070363223020135",
language = "English",
volume = "93",
pages = "327–331",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "2",

}

RIS

TY - JOUR

T1 - “2+1” Rhenium and Technetium Tricarbonyl Complexes with N,N′-Bidentate Ligands and Methyl 11-Isocyanoundecanoate

AU - Мирославов, Александр Евгеньевич

AU - Сахоненкова, Анна Павловна

AU - Тюпина, Маргарита Юрьевна

AU - Sidorenko, G. V.

PY - 2023/2/1

Y1 - 2023/2/1

N2 - Abstract: “2+1” tricarbonyl compexes [M(CO)3(N^N)CN(CH2)10COOMe]ClO4, where M = Tc or Re, N^N = 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [M(CO)3(N^N)(MeOH)]ClO4 with methyl 11-isocyanoundecanoate in methanol. The complexes were isolated and characterized by IR and 1H NMR spectroscopy and by elemental analysis. The resistance of the “2+1” tricarbonyl complexes obtained to transchelation with histidine was evaluated.

AB - Abstract: “2+1” tricarbonyl compexes [M(CO)3(N^N)CN(CH2)10COOMe]ClO4, where M = Tc or Re, N^N = 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen), were prepared by the reaction of [M(CO)3(N^N)(MeOH)]ClO4 with methyl 11-isocyanoundecanoate in methanol. The complexes were isolated and characterized by IR and 1H NMR spectroscopy and by elemental analysis. The resistance of the “2+1” tricarbonyl complexes obtained to transchelation with histidine was evaluated.

KW - bipyridine

KW - methyl 11-undecanoate

KW - phenanthroline

KW - rhenium

KW - technetium

KW - tricarbonyl complexes

UR - https://www.mendeley.com/catalogue/cec56a00-ce12-3f33-864a-813f6c405bf2/

U2 - 10.1134/S1070363223020135

DO - 10.1134/S1070363223020135

M3 - Article

VL - 93

SP - 327

EP - 331

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 2

ER -

ID: 114015376