Zn(ii) heteroleptic halide complexes with 2-halopyridines

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Zn(ii) heteroleptic halide complexes with 2-halopyridines : Features of halogen bonding in solid state. / Vershinin, Mikhail A.; Rakhmanova, Marianna I.; Novikov, Alexander S.; Sokolov, Maxim N.; Adonin, Sergey A.

In: Molecules, Vol. 26, No. 11, 3393, 03.06.2021.

Research output: Contribution to journal › Article › peer-review

Author

Vershinin, Mikhail A. ; Rakhmanova, Marianna I. ; Novikov, Alexander S. ; Sokolov, Maxim N. ; Adonin, Sergey A. / Zn(ii) heteroleptic halide complexes with 2-halopyridines : Features of halogen bonding in solid state. In: Molecules. 2021 ; Vol. 26, No. 11.

BibTeX

@article{ab31164ecb024738bfc4fd2bf33ad02c,

title = "Zn(ii) heteroleptic halide complexes with 2-halopyridines: Features of halogen bonding in solid state",

abstract = "Reactions between Zn(II) dihalides and 2-halogen-substituted pyridines 2-XPy result in a series of heteroleptic molecular complexes [(2-XPy)2ZnY2] (Y = Cl, X = Cl (1), Br (2), I (3); Y = Br, X = Cl (4), Br (5), I (6), Y = I, X = Cl (7), Br (8), and I (9)). Moreover, 1-7 are isostructural (triclinic), while 8 and 9 are monoclinic. In all cases, halogen bonding plays an important role in formation of crystal packing. Moreover, 1-9 demonstrate luminescence in asolid state; for the best emitting complexes, quantum yield (QY) exceeds 21%.",

keywords = "Halide complexes, Halogen bonding, Non-covalent interactions, Zinc, non-covalent interactions, HYDROGEN-BOND, CRYSTAL-STRUCTURE, COPPER(II), CL, NONCOVALENT INTERACTIONS, SUPRAMOLECULAR CHEMISTRY, COORDINATION-COMPOUNDS, halide complexes, M-X, MAGNETIC-PROPERTIES, zinc, halogen bonding, ZETA BASIS-SETS",

author = "Vershinin, {Mikhail A.} and Rakhmanova, {Marianna I.} and Novikov, {Alexander S.} and Sokolov, {Maxim N.} and Adonin, {Sergey A.}",

note = "Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2021",

month = jun,

day = "3",

doi = "10.3390/molecules26113393",

language = "English",

volume = "26",

journal = "Molecules",

issn = "1420-3049",

publisher = "MDPI AG",

number = "11",

}

RIS

TY - JOUR

T1 - Zn(ii) heteroleptic halide complexes with 2-halopyridines

T2 - Features of halogen bonding in solid state

AU - Vershinin, Mikhail A.

AU - Rakhmanova, Marianna I.

AU - Novikov, Alexander S.

AU - Sokolov, Maxim N.

AU - Adonin, Sergey A.

PY - 2021/6/3

Y1 - 2021/6/3

N2 - Reactions between Zn(II) dihalides and 2-halogen-substituted pyridines 2-XPy result in a series of heteroleptic molecular complexes [(2-XPy)2ZnY2] (Y = Cl, X = Cl (1), Br (2), I (3); Y = Br, X = Cl (4), Br (5), I (6), Y = I, X = Cl (7), Br (8), and I (9)). Moreover, 1-7 are isostructural (triclinic), while 8 and 9 are monoclinic. In all cases, halogen bonding plays an important role in formation of crystal packing. Moreover, 1-9 demonstrate luminescence in asolid state; for the best emitting complexes, quantum yield (QY) exceeds 21%.

AB - Reactions between Zn(II) dihalides and 2-halogen-substituted pyridines 2-XPy result in a series of heteroleptic molecular complexes [(2-XPy)2ZnY2] (Y = Cl, X = Cl (1), Br (2), I (3); Y = Br, X = Cl (4), Br (5), I (6), Y = I, X = Cl (7), Br (8), and I (9)). Moreover, 1-7 are isostructural (triclinic), while 8 and 9 are monoclinic. In all cases, halogen bonding plays an important role in formation of crystal packing. Moreover, 1-9 demonstrate luminescence in asolid state; for the best emitting complexes, quantum yield (QY) exceeds 21%.

KW - Halide complexes

KW - Halogen bonding

KW - Non-covalent interactions

KW - Zinc

KW - non-covalent interactions

KW - HYDROGEN-BOND

KW - CRYSTAL-STRUCTURE

KW - COPPER(II)

KW - CL

KW - NONCOVALENT INTERACTIONS

KW - SUPRAMOLECULAR CHEMISTRY

KW - COORDINATION-COMPOUNDS

KW - halide complexes

KW - M-X

KW - MAGNETIC-PROPERTIES

KW - zinc

KW - halogen bonding

KW - ZETA BASIS-SETS

UR - http://www.scopus.com/inward/record.url?scp=85108008033&partnerID=8YFLogxK

U2 - 10.3390/molecules26113393

DO - 10.3390/molecules26113393

M3 - Article

C2 - 34205151

AN - SCOPUS:85108008033

VL - 26

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 11

M1 - 3393

ER -

ID: 84035676