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Tricyclopropylamin und sein Radikalkation. / de Meijere, A.; Chaplinski, V.; Winsel, H.; Kusnetsov, M.A.; Rademacher, P.; Boese, R.; Haumann, T.; Traetteberg, M.; Von R.schleyer, P.; Zywietz, T.; Jiao, H.; Merstetter, P.; Gerson, F.

In: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, Vol. 38, No. 16, 1999, p. 2430-2433.

Research output: Contribution to journal › Article

Harvard

de Meijere, A, Chaplinski, V, Winsel, H, Kusnetsov, MA, Rademacher, P, Boese, R, Haumann, T, Traetteberg, M, Von R.schleyer, P, Zywietz, T, Jiao, H, Merstetter, P & Gerson, F 1999, 'Tricyclopropylamin und sein Radikalkation', ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, vol. 38, no. 16, pp. 2430-2433. https://doi.org/10.1002/(SICI)1521-3773(19990816)38:16%3C2430::AID-ANIE2430%3E3.0.CO;2-V

APA

de Meijere, A., Chaplinski, V., Winsel, H., Kusnetsov, M. A., Rademacher, P., Boese, R., Haumann, T., Traetteberg, M., Von R.schleyer, P., Zywietz, T., Jiao, H., Merstetter, P., & Gerson, F. (1999). Tricyclopropylamin und sein Radikalkation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 38(16), 2430-2433. https://doi.org/10.1002/(SICI)1521-3773(19990816)38:16%3C2430::AID-ANIE2430%3E3.0.CO;2-V

Vancouver

de Meijere A, Chaplinski V, Winsel H, Kusnetsov MA, Rademacher P, Boese R et al. Tricyclopropylamin und sein Radikalkation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 1999;38(16):2430-2433. https://doi.org/10.1002/(SICI)1521-3773(19990816)38:16%3C2430::AID-ANIE2430%3E3.0.CO;2-V

Author

de Meijere, A. ; Chaplinski, V. ; Winsel, H. ; Kusnetsov, M.A. ; Rademacher, P. ; Boese, R. ; Haumann, T. ; Traetteberg, M. ; Von R.schleyer, P. ; Zywietz, T. ; Jiao, H. ; Merstetter, P. ; Gerson, F. / Tricyclopropylamin und sein Radikalkation. In: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 1999 ; Vol. 38, No. 16. pp. 2430-2433.

BibTeX

@article{9823a31d7a574db4add57d982e997b62,
title = "Tricyclopropylamin und sein Radikalkation",
abstract = "A surprisingly high first vertical ionization energy (8.44 eV) and an unusually high oxidation potential are exibited by tricyclopropylamine (1)—in sharp contrast to triisopropylamine. These are attributed to the near-tetrahedral geometry of 1 at the N atom and the perpendicular orientation—with respect to the N-orbital axis—of the cyclopropyl groups. γ-Irradiation of 1 led to the radical cation 1.+, which, in accord with computations, has a planar C3h-symmetrical structure. The EPR-spectroscopic and computational results disclose a dramatic, previously not reported, conformational change on going from 1 to 1.+.",
author = "{de Meijere}, A. and V. Chaplinski and H. Winsel and M.A. Kusnetsov and P. Rademacher and R. Boese and T. Haumann and M. Traetteberg and {Von R.schleyer}, P. and T. Zywietz and H. Jiao and P. Merstetter and F. Gerson",
year = "1999",
doi = "10.1002/(SICI)1521-3773(19990816)38:16%3C2430::AID-ANIE2430%3E3.0.CO;2-V",
language = "немецкий",
volume = "38",
pages = "2430--2433",
journal = "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION",
issn = "1433-7851",
publisher = "Wiley-Blackwell",
number = "16",

}

RIS

TY - JOUR

T1 - Tricyclopropylamin und sein Radikalkation

AU - de Meijere, A.

AU - Chaplinski, V.

AU - Winsel, H.

AU - Kusnetsov, M.A.

AU - Rademacher, P.

AU - Boese, R.

AU - Haumann, T.

AU - Traetteberg, M.

AU - Von R.schleyer, P.

AU - Zywietz, T.

AU - Jiao, H.

AU - Merstetter, P.

AU - Gerson, F.

PY - 1999

Y1 - 1999

N2 - A surprisingly high first vertical ionization energy (8.44 eV) and an unusually high oxidation potential are exibited by tricyclopropylamine (1)—in sharp contrast to triisopropylamine. These are attributed to the near-tetrahedral geometry of 1 at the N atom and the perpendicular orientation—with respect to the N-orbital axis—of the cyclopropyl groups. γ-Irradiation of 1 led to the radical cation 1.+, which, in accord with computations, has a planar C3h-symmetrical structure. The EPR-spectroscopic and computational results disclose a dramatic, previously not reported, conformational change on going from 1 to 1.+.

AB - A surprisingly high first vertical ionization energy (8.44 eV) and an unusually high oxidation potential are exibited by tricyclopropylamine (1)—in sharp contrast to triisopropylamine. These are attributed to the near-tetrahedral geometry of 1 at the N atom and the perpendicular orientation—with respect to the N-orbital axis—of the cyclopropyl groups. γ-Irradiation of 1 led to the radical cation 1.+, which, in accord with computations, has a planar C3h-symmetrical structure. The EPR-spectroscopic and computational results disclose a dramatic, previously not reported, conformational change on going from 1 to 1.+.

U2 - 10.1002/(SICI)1521-3773(19990816)38:16%3C2430::AID-ANIE2430%3E3.0.CO;2-V

DO - 10.1002/(SICI)1521-3773(19990816)38:16%3C2430::AID-ANIE2430%3E3.0.CO;2-V

M3 - статья

VL - 38

SP - 2430

EP - 2433

JO - ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

JF - ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SN - 1433-7851

IS - 16

ER -

ID: 5139768