Standard

Thermodynamics of vesicles. / Rusanov, A. I.

In: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 76, No. C, 08.09.1993, p. 7-13.

Research output: Contribution to journal › Article › peer-review

Harvard

Rusanov, AI 1993, 'Thermodynamics of vesicles', Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 76, no. C, pp. 7-13. https://doi.org/10.1016/0927-7757(93)80055-J

APA

Rusanov, A. I. (1993). Thermodynamics of vesicles. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 76(C), 7-13. https://doi.org/10.1016/0927-7757(93)80055-J

Vancouver

Rusanov AI. Thermodynamics of vesicles. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 1993 Sep 8;76(C):7-13. https://doi.org/10.1016/0927-7757(93)80055-J

Author

Rusanov, A. I. / Thermodynamics of vesicles. In: Colloids and Surfaces A: Physicochemical and Engineering Aspects. 1993 ; Vol. 76, No. C. pp. 7-13.

BibTeX

@article{3175b310c4b04ea9985912deeea72680,
title = "Thermodynamics of vesicles",
abstract = "Vesicles in a state of mechanical equilibrium (but not necessarily in a state of diffusional equilibrium) are considered. The packing conditions are derived for vesicles on the basis of considering a vesicle as a whole and of a more detailed analysis of both the monolayers of the vesicle. The packing conditions prove to be different for the outer and the inner monolayers of the vesicle. The generalized Gibbs-Curie principle is derived for a vesicle. Some difficulties which arise are related to the fact that, in contrast to the case of micelles and small crystals, the vesicle in a state of difrusional non-equilibrium should be treated as a three-phase system with two interfaces. The generalized Gibbs-Curie principle is applied to the analysis of the vesicle-disc-like micelle phase transition. Conditions when the formation of vesicles becomes energetically more favorable than that of disc-like micelles are shown to be easily realizable. Under such conditions, vesicles form spontaneously from bilayers without ultrasonic treatment.",
keywords = "Gibbs-Curie principle, micelle transition, thermodynamics, vesicles.",
author = "Rusanov, {A. I.}",
year = "1993",
month = sep,
day = "8",
doi = "10.1016/0927-7757(93)80055-J",
language = "English",
volume = "76",
pages = "7--13",
journal = "Colloids and Surfaces A: Physicochemical and Engineering Aspects",
issn = "0927-7757",
publisher = "Elsevier",
number = "C",

}

RIS

TY - JOUR

T1 - Thermodynamics of vesicles

AU - Rusanov, A. I.

PY - 1993/9/8

Y1 - 1993/9/8

N2 - Vesicles in a state of mechanical equilibrium (but not necessarily in a state of diffusional equilibrium) are considered. The packing conditions are derived for vesicles on the basis of considering a vesicle as a whole and of a more detailed analysis of both the monolayers of the vesicle. The packing conditions prove to be different for the outer and the inner monolayers of the vesicle. The generalized Gibbs-Curie principle is derived for a vesicle. Some difficulties which arise are related to the fact that, in contrast to the case of micelles and small crystals, the vesicle in a state of difrusional non-equilibrium should be treated as a three-phase system with two interfaces. The generalized Gibbs-Curie principle is applied to the analysis of the vesicle-disc-like micelle phase transition. Conditions when the formation of vesicles becomes energetically more favorable than that of disc-like micelles are shown to be easily realizable. Under such conditions, vesicles form spontaneously from bilayers without ultrasonic treatment.

AB - Vesicles in a state of mechanical equilibrium (but not necessarily in a state of diffusional equilibrium) are considered. The packing conditions are derived for vesicles on the basis of considering a vesicle as a whole and of a more detailed analysis of both the monolayers of the vesicle. The packing conditions prove to be different for the outer and the inner monolayers of the vesicle. The generalized Gibbs-Curie principle is derived for a vesicle. Some difficulties which arise are related to the fact that, in contrast to the case of micelles and small crystals, the vesicle in a state of difrusional non-equilibrium should be treated as a three-phase system with two interfaces. The generalized Gibbs-Curie principle is applied to the analysis of the vesicle-disc-like micelle phase transition. Conditions when the formation of vesicles becomes energetically more favorable than that of disc-like micelles are shown to be easily realizable. Under such conditions, vesicles form spontaneously from bilayers without ultrasonic treatment.

KW - Gibbs-Curie principle

KW - micelle transition

KW - thermodynamics

KW - vesicles.

UR - http://www.scopus.com/inward/record.url?scp=0343360862&partnerID=8YFLogxK

U2 - 10.1016/0927-7757(93)80055-J

DO - 10.1016/0927-7757(93)80055-J

M3 - Article

AN - SCOPUS:0343360862

VL - 76

SP - 7

EP - 13

JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects

JF - Colloids and Surfaces A: Physicochemical and Engineering Aspects

SN - 0927-7757

IS - C

ER -

ID: 95722327