Research output: Contribution to journal › Article › peer-review
The stabilization of decabromide {Br10}2− anion in the structure of Sb(V) bromide complex. / Bondarenko, Mikhail A.; Novikov, Alexander S.; Fedin, Vladimir P.; Sokolov, Maxim N.; Adonin, Sergey A.
In: Journal of Coordination Chemistry, Vol. 73, No. 20-22, 26.10.2020, p. 3038-3043.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - The stabilization of decabromide {Br10}2− anion in the structure of Sb(V) bromide complex
AU - Bondarenko, Mikhail A.
AU - Novikov, Alexander S.
AU - Fedin, Vladimir P.
AU - Sokolov, Maxim N.
AU - Adonin, Sergey A.
N1 - Publisher Copyright: © 2020 Informa UK Limited, trading as Taylor & Francis Group.
PY - 2020/10/26
Y1 - 2020/10/26
N2 - The supramolecular decabromide anion {Br10}2− was found in the structure of polybromide-bromoantimonate complex (4-MePyC3)2{[SbBr6]2{Br10}} (1) (4-MePyC3 = 1,1′(propane-1,3-diyl)bis(4-methylpyridin)-1-ium dication). {Br10}2− is a Z-shaped dimer of pentabromide Br5− units connected via terminal Br atoms. Each {Br5} forms halogen bonding with one [SbVBr6]− anion.
AB - The supramolecular decabromide anion {Br10}2− was found in the structure of polybromide-bromoantimonate complex (4-MePyC3)2{[SbBr6]2{Br10}} (1) (4-MePyC3 = 1,1′(propane-1,3-diyl)bis(4-methylpyridin)-1-ium dication). {Br10}2− is a Z-shaped dimer of pentabromide Br5− units connected via terminal Br atoms. Each {Br5} forms halogen bonding with one [SbVBr6]− anion.
KW - Antimony
KW - halogen bonding
KW - polybromide
KW - polyhalides
KW - supramolecular contacts
KW - INTERPLAY
KW - VAN
KW - RADII
UR - http://www.scopus.com/inward/record.url?scp=85094563152&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/d427c99a-1030-394a-b43e-f288990eadf0/
U2 - 10.1080/00958972.2020.1837785
DO - 10.1080/00958972.2020.1837785
M3 - Article
AN - SCOPUS:85094563152
VL - 73
SP - 3038
EP - 3043
JO - Journal of Coordination Chemistry
JF - Journal of Coordination Chemistry
SN - 0095-8972
IS - 20-22
ER -
ID: 70760766