DOI

The supramolecular decabromide anion {Br10}2− was found in the structure of polybromide-bromoantimonate complex (4-MePyC3)2{[SbBr6]2{Br10}} (1) (4-MePyC3 = 1,1′(propane-1,3-diyl)bis(4-methylpyridin)-1-ium dication). {Br10}2− is a Z-shaped dimer of pentabromide Br5− units connected via terminal Br atoms. Each {Br5} forms halogen bonding with one [SbVBr6]− anion.

Original languageEnglish
Pages (from-to)3038-3043
Number of pages6
JournalJournal of Coordination Chemistry
Volume73
Issue number20-22
DOIs
StatePublished - 26 Oct 2020

    Scopus subject areas

  • Materials Chemistry
  • Physical and Theoretical Chemistry

    Research areas

  • Antimony, halogen bonding, polybromide, polyhalides, supramolecular contacts, INTERPLAY, VAN, RADII

ID: 70760766