Standard

The optimization of ipso-chlorination reaction of calix[4]arenes. / Trushina, Ekaterina; Kryukov, Dmitry; Prokhorova, Polina.

Modern Synthetic Methodologies for Creating Drugs and Functional Materials, MOSM 2019: Proceedings of the III International Conference. ed. / Grigory V. Zyryanov; Sougata Santra; Leila K. Sadieva. American Institute of Physics, 2020. 0018163 (AIP Conference Proceedings; Vol. 2280).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Research › peer-review

Harvard

Trushina, E, Kryukov, D & Prokhorova, P 2020, The optimization of ipso-chlorination reaction of calix[4]arenes. in GV Zyryanov, S Santra & LK Sadieva (eds), Modern Synthetic Methodologies for Creating Drugs and Functional Materials, MOSM 2019: Proceedings of the III International Conference., 0018163, AIP Conference Proceedings, vol. 2280, American Institute of Physics, 3rd International Conference on Modern Synthetic Methodologies for Creating Drugs and Functional Materials, MOSM 2019, Yekaterinburg, Russian Federation, 13/11/19. https://doi.org/10.1063/5.0018163

APA

Trushina, E., Kryukov, D., & Prokhorova, P. (2020). The optimization of ipso-chlorination reaction of calix[4]arenes. In G. V. Zyryanov, S. Santra, & L. K. Sadieva (Eds.), Modern Synthetic Methodologies for Creating Drugs and Functional Materials, MOSM 2019: Proceedings of the III International Conference [0018163] (AIP Conference Proceedings; Vol. 2280). American Institute of Physics. https://doi.org/10.1063/5.0018163

Vancouver

Trushina E, Kryukov D, Prokhorova P. The optimization of ipso-chlorination reaction of calix[4]arenes. In Zyryanov GV, Santra S, Sadieva LK, editors, Modern Synthetic Methodologies for Creating Drugs and Functional Materials, MOSM 2019: Proceedings of the III International Conference. American Institute of Physics. 2020. 0018163. (AIP Conference Proceedings). https://doi.org/10.1063/5.0018163

Author

Trushina, Ekaterina ; Kryukov, Dmitry ; Prokhorova, Polina. / The optimization of ipso-chlorination reaction of calix[4]arenes. Modern Synthetic Methodologies for Creating Drugs and Functional Materials, MOSM 2019: Proceedings of the III International Conference. editor / Grigory V. Zyryanov ; Sougata Santra ; Leila K. Sadieva. American Institute of Physics, 2020. (AIP Conference Proceedings).

BibTeX

@inproceedings{d5c75477439c48f39cde3046cb8cc3ff,
title = "The optimization of ipso-chlorination reaction of calix[4]arenes",
abstract = "The study is devoted to the detailed investigation of the ipso-chlorination reaction of calixarenes and search of an optimal combination of chlorinating reagents. This factor was varied in a number of experiments. It was established that the presence of sulphuryl chloride and the acidic proton is a necessary condition for successful ipso-chlorination of calix[4]arenes. The addition of any of phosphorus chlorides accelerates reaction speed and increases process yield. So the most promising chlorination mixture was that SO2Cl2 (4 eq.), POCl3 (1 eq.) and glacial acetic acid (1 eq.) which provided 64% yield of the desired compound after two days of the experiment.",
author = "Ekaterina Trushina and Dmitry Kryukov and Polina Prokhorova",
note = "Publisher Copyright: {\textcopyright} 2020 Author(s).; 3rd International Conference on Modern Synthetic Methodologies for Creating Drugs and Functional Materials, MOSM 2019 ; Conference date: 13-11-2019 Through 16-11-2019",
year = "2020",
month = nov,
day = "4",
doi = "10.1063/5.0018163",
language = "English",
series = "AIP Conference Proceedings",
publisher = "American Institute of Physics",
editor = "Zyryanov, {Grigory V.} and Sougata Santra and Sadieva, {Leila K.}",
booktitle = "Modern Synthetic Methodologies for Creating Drugs and Functional Materials, MOSM 2019",
address = "United States",

}

RIS

TY - GEN

T1 - The optimization of ipso-chlorination reaction of calix[4]arenes

AU - Trushina, Ekaterina

AU - Kryukov, Dmitry

AU - Prokhorova, Polina

N1 - Publisher Copyright: © 2020 Author(s).

PY - 2020/11/4

Y1 - 2020/11/4

N2 - The study is devoted to the detailed investigation of the ipso-chlorination reaction of calixarenes and search of an optimal combination of chlorinating reagents. This factor was varied in a number of experiments. It was established that the presence of sulphuryl chloride and the acidic proton is a necessary condition for successful ipso-chlorination of calix[4]arenes. The addition of any of phosphorus chlorides accelerates reaction speed and increases process yield. So the most promising chlorination mixture was that SO2Cl2 (4 eq.), POCl3 (1 eq.) and glacial acetic acid (1 eq.) which provided 64% yield of the desired compound after two days of the experiment.

AB - The study is devoted to the detailed investigation of the ipso-chlorination reaction of calixarenes and search of an optimal combination of chlorinating reagents. This factor was varied in a number of experiments. It was established that the presence of sulphuryl chloride and the acidic proton is a necessary condition for successful ipso-chlorination of calix[4]arenes. The addition of any of phosphorus chlorides accelerates reaction speed and increases process yield. So the most promising chlorination mixture was that SO2Cl2 (4 eq.), POCl3 (1 eq.) and glacial acetic acid (1 eq.) which provided 64% yield of the desired compound after two days of the experiment.

UR - http://www.scopus.com/inward/record.url?scp=85096445665&partnerID=8YFLogxK

U2 - 10.1063/5.0018163

DO - 10.1063/5.0018163

M3 - Conference contribution

AN - SCOPUS:85096445665

T3 - AIP Conference Proceedings

BT - Modern Synthetic Methodologies for Creating Drugs and Functional Materials, MOSM 2019

A2 - Zyryanov, Grigory V.

A2 - Santra, Sougata

A2 - Sadieva, Leila K.

PB - American Institute of Physics

T2 - 3rd International Conference on Modern Synthetic Methodologies for Creating Drugs and Functional Materials, MOSM 2019

Y2 - 13 November 2019 through 16 November 2019

ER -

ID: 84915709