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The AM-4 Family of Layered Titanosilicates: Single-Crystal-to-Single-Crystal Transformation, Synthesis and Ionic Conductivity. / Kalashnikova, Galina O.; Krivovichev, Sergey V.; Yakovenchuk, Victor N.; Selivanova, Ekaterina A.; Avdontceva, Margarita S.; Ivanyuk, Gregory Yu.; Pakhomovsky, Yakov A.; Gryaznova, Darya V.; Kabanova, Natalya A.; Morkhova, Yelizaveta A.; Sinel’shchikova, Olga Yu.; Bocharov, Vladimir N.; Nikolaev, Anatoly I.; Goychuk, Olga F.; Volkov, Sergei N.; Panikorovskii, Taras L.

In: Materials, Vol. 17, No. 1, 111, 2024.

Research output: Contribution to journalArticlepeer-review

Harvard

Kalashnikova, GO, Krivovichev, SV, Yakovenchuk, VN, Selivanova, EA, Avdontceva, MS, Ivanyuk, GY, Pakhomovsky, YA, Gryaznova, DV, Kabanova, NA, Morkhova, YA, Sinel’shchikova, OY, Bocharov, VN, Nikolaev, AI, Goychuk, OF, Volkov, SN & Panikorovskii, TL 2024, 'The AM-4 Family of Layered Titanosilicates: Single-Crystal-to-Single-Crystal Transformation, Synthesis and Ionic Conductivity', Materials, vol. 17, no. 1, 111. https://doi.org/10.3390/ma17010111

APA

Kalashnikova, G. O., Krivovichev, S. V., Yakovenchuk, V. N., Selivanova, E. A., Avdontceva, M. S., Ivanyuk, G. Y., Pakhomovsky, Y. A., Gryaznova, D. V., Kabanova, N. A., Morkhova, Y. A., Sinel’shchikova, O. Y., Bocharov, V. N., Nikolaev, A. I., Goychuk, O. F., Volkov, S. N., & Panikorovskii, T. L. (2024). The AM-4 Family of Layered Titanosilicates: Single-Crystal-to-Single-Crystal Transformation, Synthesis and Ionic Conductivity. Materials, 17(1), [111]. https://doi.org/10.3390/ma17010111

Vancouver

Author

Kalashnikova, Galina O. ; Krivovichev, Sergey V. ; Yakovenchuk, Victor N. ; Selivanova, Ekaterina A. ; Avdontceva, Margarita S. ; Ivanyuk, Gregory Yu. ; Pakhomovsky, Yakov A. ; Gryaznova, Darya V. ; Kabanova, Natalya A. ; Morkhova, Yelizaveta A. ; Sinel’shchikova, Olga Yu. ; Bocharov, Vladimir N. ; Nikolaev, Anatoly I. ; Goychuk, Olga F. ; Volkov, Sergei N. ; Panikorovskii, Taras L. / The AM-4 Family of Layered Titanosilicates: Single-Crystal-to-Single-Crystal Transformation, Synthesis and Ionic Conductivity. In: Materials. 2024 ; Vol. 17, No. 1.

BibTeX

@article{d28c119cbdee4c3f91019306c845ea01,
title = "The AM-4 Family of Layered Titanosilicates: Single-Crystal-to-Single-Crystal Transformation, Synthesis and Ionic Conductivity",
abstract = "Flexible crystal() structures, which exhibit() single-crystal()-to-single-crystal() (SCSC) transformations(), are attracting attention() in many applied aspects: magnetic() switches, catalysis, ferroelectrics and sorption. Acid treatment() for titanosilicate material() AM-4 and natural() compounds with the same structures led to SCSC transformation() by loss() Na +, Li + and Zn 2+ cations with large structural() changes (20% of the unit()-cell() volume()). The conservation() of crystallinity through complex() transformation() is possible due() to the formation() of a strong hydrogen bonding() system(). The mechanism() of transformation() has been characterized using single-crystal() X-ray() diffraction analysis(), powder() diffraction, Rietvield refinement, Raman spectroscopy and electron microscopy. The low migration() energy() of cations in the considered materials() is confirmed using bond()-valence and density() functional() theory() calculations, and the ion conductivity of the AM-4 family's materials() has been experimentally verified. ",
author = "Kalashnikova, {Galina O.} and Krivovichev, {Sergey V.} and Yakovenchuk, {Victor N.} and Selivanova, {Ekaterina A.} and Avdontceva, {Margarita S.} and Ivanyuk, {Gregory Yu.} and Pakhomovsky, {Yakov A.} and Gryaznova, {Darya V.} and Kabanova, {Natalya A.} and Morkhova, {Yelizaveta A.} and Sinel{\textquoteright}shchikova, {Olga Yu.} and Bocharov, {Vladimir N.} and Nikolaev, {Anatoly I.} and Goychuk, {Olga F.} and Volkov, {Sergei N.} and Panikorovskii, {Taras L.}",
year = "2024",
doi = "10.3390/ma17010111",
language = "English",
volume = "17",
journal = "Materials",
issn = "1996-1944",
publisher = "MDPI AG",
number = "1",

}

RIS

TY - JOUR

T1 - The AM-4 Family of Layered Titanosilicates: Single-Crystal-to-Single-Crystal Transformation, Synthesis and Ionic Conductivity

AU - Kalashnikova, Galina O.

AU - Krivovichev, Sergey V.

AU - Yakovenchuk, Victor N.

AU - Selivanova, Ekaterina A.

AU - Avdontceva, Margarita S.

AU - Ivanyuk, Gregory Yu.

AU - Pakhomovsky, Yakov A.

AU - Gryaznova, Darya V.

AU - Kabanova, Natalya A.

AU - Morkhova, Yelizaveta A.

AU - Sinel’shchikova, Olga Yu.

AU - Bocharov, Vladimir N.

AU - Nikolaev, Anatoly I.

AU - Goychuk, Olga F.

AU - Volkov, Sergei N.

AU - Panikorovskii, Taras L.

PY - 2024

Y1 - 2024

N2 - Flexible crystal() structures, which exhibit() single-crystal()-to-single-crystal() (SCSC) transformations(), are attracting attention() in many applied aspects: magnetic() switches, catalysis, ferroelectrics and sorption. Acid treatment() for titanosilicate material() AM-4 and natural() compounds with the same structures led to SCSC transformation() by loss() Na +, Li + and Zn 2+ cations with large structural() changes (20% of the unit()-cell() volume()). The conservation() of crystallinity through complex() transformation() is possible due() to the formation() of a strong hydrogen bonding() system(). The mechanism() of transformation() has been characterized using single-crystal() X-ray() diffraction analysis(), powder() diffraction, Rietvield refinement, Raman spectroscopy and electron microscopy. The low migration() energy() of cations in the considered materials() is confirmed using bond()-valence and density() functional() theory() calculations, and the ion conductivity of the AM-4 family's materials() has been experimentally verified.

AB - Flexible crystal() structures, which exhibit() single-crystal()-to-single-crystal() (SCSC) transformations(), are attracting attention() in many applied aspects: magnetic() switches, catalysis, ferroelectrics and sorption. Acid treatment() for titanosilicate material() AM-4 and natural() compounds with the same structures led to SCSC transformation() by loss() Na +, Li + and Zn 2+ cations with large structural() changes (20% of the unit()-cell() volume()). The conservation() of crystallinity through complex() transformation() is possible due() to the formation() of a strong hydrogen bonding() system(). The mechanism() of transformation() has been characterized using single-crystal() X-ray() diffraction analysis(), powder() diffraction, Rietvield refinement, Raman spectroscopy and electron microscopy. The low migration() energy() of cations in the considered materials() is confirmed using bond()-valence and density() functional() theory() calculations, and the ion conductivity of the AM-4 family's materials() has been experimentally verified.

UR - https://www.mendeley.com/catalogue/b89d7181-ddfe-3fd0-a6f5-4311d865aa32/

U2 - 10.3390/ma17010111

DO - 10.3390/ma17010111

M3 - Article

C2 - 38203965

VL - 17

JO - Materials

JF - Materials

SN - 1996-1944

IS - 1

M1 - 111

ER -

ID: 116381738