Research output: Contribution to journal › Article › peer-review
The AM-4 Family of Layered Titanosilicates: Single-Crystal-to-Single-Crystal Transformation, Synthesis and Ionic Conductivity. / Kalashnikova, Galina O.; Krivovichev, Sergey V.; Yakovenchuk, Victor N.; Selivanova, Ekaterina A.; Avdontceva, Margarita S.; Ivanyuk, Gregory Yu.; Pakhomovsky, Yakov A.; Gryaznova, Darya V.; Kabanova, Natalya A.; Morkhova, Yelizaveta A.; Sinel’shchikova, Olga Yu.; Bocharov, Vladimir N.; Nikolaev, Anatoly I.; Goychuk, Olga F.; Volkov, Sergei N.; Panikorovskii, Taras L.
In: Materials, Vol. 17, No. 1, 111, 2024.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - The AM-4 Family of Layered Titanosilicates: Single-Crystal-to-Single-Crystal Transformation, Synthesis and Ionic Conductivity
AU - Kalashnikova, Galina O.
AU - Krivovichev, Sergey V.
AU - Yakovenchuk, Victor N.
AU - Selivanova, Ekaterina A.
AU - Avdontceva, Margarita S.
AU - Ivanyuk, Gregory Yu.
AU - Pakhomovsky, Yakov A.
AU - Gryaznova, Darya V.
AU - Kabanova, Natalya A.
AU - Morkhova, Yelizaveta A.
AU - Sinel’shchikova, Olga Yu.
AU - Bocharov, Vladimir N.
AU - Nikolaev, Anatoly I.
AU - Goychuk, Olga F.
AU - Volkov, Sergei N.
AU - Panikorovskii, Taras L.
PY - 2024
Y1 - 2024
N2 - Flexible crystal() structures, which exhibit() single-crystal()-to-single-crystal() (SCSC) transformations(), are attracting attention() in many applied aspects: magnetic() switches, catalysis, ferroelectrics and sorption. Acid treatment() for titanosilicate material() AM-4 and natural() compounds with the same structures led to SCSC transformation() by loss() Na +, Li + and Zn 2+ cations with large structural() changes (20% of the unit()-cell() volume()). The conservation() of crystallinity through complex() transformation() is possible due() to the formation() of a strong hydrogen bonding() system(). The mechanism() of transformation() has been characterized using single-crystal() X-ray() diffraction analysis(), powder() diffraction, Rietvield refinement, Raman spectroscopy and electron microscopy. The low migration() energy() of cations in the considered materials() is confirmed using bond()-valence and density() functional() theory() calculations, and the ion conductivity of the AM-4 family's materials() has been experimentally verified.
AB - Flexible crystal() structures, which exhibit() single-crystal()-to-single-crystal() (SCSC) transformations(), are attracting attention() in many applied aspects: magnetic() switches, catalysis, ferroelectrics and sorption. Acid treatment() for titanosilicate material() AM-4 and natural() compounds with the same structures led to SCSC transformation() by loss() Na +, Li + and Zn 2+ cations with large structural() changes (20% of the unit()-cell() volume()). The conservation() of crystallinity through complex() transformation() is possible due() to the formation() of a strong hydrogen bonding() system(). The mechanism() of transformation() has been characterized using single-crystal() X-ray() diffraction analysis(), powder() diffraction, Rietvield refinement, Raman spectroscopy and electron microscopy. The low migration() energy() of cations in the considered materials() is confirmed using bond()-valence and density() functional() theory() calculations, and the ion conductivity of the AM-4 family's materials() has been experimentally verified.
UR - https://www.mendeley.com/catalogue/b89d7181-ddfe-3fd0-a6f5-4311d865aa32/
U2 - 10.3390/ma17010111
DO - 10.3390/ma17010111
M3 - Article
C2 - 38203965
VL - 17
JO - Materials
JF - Materials
SN - 1996-1944
IS - 1
M1 - 111
ER -
ID: 116381738