DOI

  • Sergey A. Adonin
  • Igor D. Gorokh
  • Alexander S. Novikov
  • Andrey N. Usoltsev
  • Maxim N. Sokolov
  • Vladimir P. Fedin

Tetranuclear bromobismuthate anion [Bi 4 Br 18 ] 6− of a brand-new structural type was found in a complex ((3,5-MePy)C 2 ) 3 [Bi 4 Br 18 ] (1) which was obtained by reaction of 1,1′-(ethane-1,2-diyl)bis(3,5-dimethylpyridin-1-ium) dibromide ((3,5-MePy)C 2 Br 2 ) with solution of Bi 2 O 3 in HBr. Hirshfeld surface analysis was performed for the crystal structure of 1, revealing the nature of interactions in solid state.

Original languageEnglish
Pages (from-to)72-74
Number of pages3
JournalInorganic Chemistry Communications
Volume103
DOIs
StatePublished - 1 May 2019

    Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

    Research areas

  • Bismuth, Crystal structure, Halide complexes, Halometalate, Hirshfeld surface analysis

ID: 39841943