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tert-Butyl 3-Diazo-2-oxopyrrolidine-1-carboxylate – A New Reagent for Introduction of the 2-Oxopyrrolidin-3-yl Motif via RhII-Catalyzed X–H Insertion Reactions. / Zhukovsky, Daniil; Dar'in, Dmitry; Krasavin, Mikhail.

In: European Journal of Organic Chemistry, Vol. 2020, No. 20, 29.05.2020, p. 3013-3018.

Research output: Contribution to journal › Article › peer-review

Harvard

Zhukovsky, D, Dar'in, D & Krasavin, M 2020, 'tert-Butyl 3-Diazo-2-oxopyrrolidine-1-carboxylate – A New Reagent for Introduction of the 2-Oxopyrrolidin-3-yl Motif via RhII-Catalyzed X–H Insertion Reactions', European Journal of Organic Chemistry, vol. 2020, no. 20, pp. 3013-3018. https://doi.org/10.1002/ejoc.202000067

APA

Zhukovsky, D., Dar'in, D., & Krasavin, M. (2020). tert-Butyl 3-Diazo-2-oxopyrrolidine-1-carboxylate – A New Reagent for Introduction of the 2-Oxopyrrolidin-3-yl Motif via RhII-Catalyzed X–H Insertion Reactions. European Journal of Organic Chemistry, 2020(20), 3013-3018. https://doi.org/10.1002/ejoc.202000067

Vancouver

Zhukovsky D, Dar'in D, Krasavin M. tert-Butyl 3-Diazo-2-oxopyrrolidine-1-carboxylate – A New Reagent for Introduction of the 2-Oxopyrrolidin-3-yl Motif via RhII-Catalyzed X–H Insertion Reactions. European Journal of Organic Chemistry. 2020 May 29;2020(20):3013-3018. https://doi.org/10.1002/ejoc.202000067

Author

Zhukovsky, Daniil ; Dar'in, Dmitry ; Krasavin, Mikhail. / tert-Butyl 3-Diazo-2-oxopyrrolidine-1-carboxylate – A New Reagent for Introduction of the 2-Oxopyrrolidin-3-yl Motif via RhII-Catalyzed X–H Insertion Reactions. In: European Journal of Organic Chemistry. 2020 ; Vol. 2020, No. 20. pp. 3013-3018.

BibTeX

@article{bdd42db5997b4f20b21da64be831219a,
title = "tert-Butyl 3-Diazo-2-oxopyrrolidine-1-carboxylate – A New Reagent for Introduction of the 2-Oxopyrrolidin-3-yl Motif via RhII-Catalyzed X–H Insertion Reactions",
abstract = "tert-Butyl 3-diazo-2-oxopyrrolidine-1-carboxylate synthesized on multigram scale has been employed to introduce a privileged NH-2-pyrrolidone moiety via oxygen, sulfur and nitrogen atom to partner molecules via RhII-catalyzed X–H insertion followed by Boc group removal. Further manipulation of pyrrolidine moiety has been exemplified.",
keywords = "2-pyrrolidone, Diazo transfer, Lactam reduction, Privileged structures, RhII-catalyzed X–H insertion, RhII-catalyzed X-H insertion",
author = "Daniil Zhukovsky and Dmitry Dar'in and Mikhail Krasavin",
year = "2020",
month = may,
day = "29",
doi = "10.1002/ejoc.202000067",
language = "English",
volume = "2020",
pages = "3013--3018",
journal = "European Journal of Organic Chemistry",
issn = "1434-193X",
publisher = "Wiley-Blackwell",
number = "20",

}

RIS

TY - JOUR

T1 - tert-Butyl 3-Diazo-2-oxopyrrolidine-1-carboxylate – A New Reagent for Introduction of the 2-Oxopyrrolidin-3-yl Motif via RhII-Catalyzed X–H Insertion Reactions

AU - Zhukovsky, Daniil

AU - Dar'in, Dmitry

AU - Krasavin, Mikhail

PY - 2020/5/29

Y1 - 2020/5/29

N2 - tert-Butyl 3-diazo-2-oxopyrrolidine-1-carboxylate synthesized on multigram scale has been employed to introduce a privileged NH-2-pyrrolidone moiety via oxygen, sulfur and nitrogen atom to partner molecules via RhII-catalyzed X–H insertion followed by Boc group removal. Further manipulation of pyrrolidine moiety has been exemplified.

AB - tert-Butyl 3-diazo-2-oxopyrrolidine-1-carboxylate synthesized on multigram scale has been employed to introduce a privileged NH-2-pyrrolidone moiety via oxygen, sulfur and nitrogen atom to partner molecules via RhII-catalyzed X–H insertion followed by Boc group removal. Further manipulation of pyrrolidine moiety has been exemplified.

KW - 2-pyrrolidone

KW - Diazo transfer

KW - Lactam reduction

KW - Privileged structures

KW - RhII-catalyzed X–H insertion

KW - RhII-catalyzed X-H insertion

UR - http://www.scopus.com/inward/record.url?scp=85081660045&partnerID=8YFLogxK

U2 - 10.1002/ejoc.202000067

DO - 10.1002/ejoc.202000067

M3 - Article

AN - SCOPUS:85081660045

VL - 2020

SP - 3013

EP - 3018

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

SN - 1434-193X

IS - 20

ER -

ID: 52504934