Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions

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Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions. / Kinzhalov, M. A. ; Kashina, M. V. ; Mikherdov, A. S. ; Katkova, S. A. ; Suslonov, V. V. .

In: Russian Journal of General Chemistry, Vol. 88, No. 6, 8, 06.2018, p. 1180-1187.

Research output: Contribution to journal › Article

BibTeX

@article{78eff4f93af04dc2b0793a4461598468,

title = "Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions",

abstract = "Phosphine isocyanide complexes cis-[PtCl 2(CNMes)(P)] with mesitylisocyanide and phoshine ligands were synthesized in yields of 92‒98%. The products were characterized by mass spectrometry, IR and 1H NMR, COSY, NOESY, HSQC, and HMBC spectroscopy, and X-ray diffraction analysis. The solid-state and solution structures of the complexes and their stability in isomerization and ligand disproportionation reactions were studied. ",

keywords = "isocyanides, phosphines, platinum complexes, HYDROSILYLATION, X-RAY-STRUCTURE, CRYSTAL-STRUCTURES, ISONITRILES, ALKYNES, METAL COMPLEXES, COLOR, EMISSION, PALLADIUM(II), CATALYSTS",

author = "Kinzhalov, {M. A.} and Kashina, {M. V.} and Mikherdov, {A. S.} and Katkova, {S. A.} and Suslonov, {V. V.}",

note = "Kinzhalov, M.A., Kashina, M.V., Mikherdov, A.S. et al. Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions. Russ J Gen Chem 88, 1180–1187 (2018). https://doi.org/10.1134/S107036321806021X",

year = "2018",

month = jun,

doi = "10.1134/S107036321806021X",

language = "English",

volume = "88",

pages = "1180--1187",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "6",

}

RIS

TY - JOUR

T1 - Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions

AU - Kinzhalov, M. A.

AU - Kashina, M. V.

AU - Mikherdov, A. S.

AU - Katkova, S. A.

AU - Suslonov, V. V.

N1 - Kinzhalov, M.A., Kashina, M.V., Mikherdov, A.S. et al. Synthesis of Platinum(II) Phoshine Isocyanide Complexes and Study of Their Stability in Isomerization and Ligand Disproportionation Reactions. Russ J Gen Chem 88, 1180–1187 (2018). https://doi.org/10.1134/S107036321806021X

PY - 2018/6

Y1 - 2018/6

N2 - Phosphine isocyanide complexes cis-[PtCl 2(CNMes)(P)] with mesitylisocyanide and phoshine ligands were synthesized in yields of 92‒98%. The products were characterized by mass spectrometry, IR and 1H NMR, COSY, NOESY, HSQC, and HMBC spectroscopy, and X-ray diffraction analysis. The solid-state and solution structures of the complexes and their stability in isomerization and ligand disproportionation reactions were studied.

AB - Phosphine isocyanide complexes cis-[PtCl 2(CNMes)(P)] with mesitylisocyanide and phoshine ligands were synthesized in yields of 92‒98%. The products were characterized by mass spectrometry, IR and 1H NMR, COSY, NOESY, HSQC, and HMBC spectroscopy, and X-ray diffraction analysis. The solid-state and solution structures of the complexes and their stability in isomerization and ligand disproportionation reactions were studied.

KW - isocyanides

KW - phosphines

KW - platinum complexes

KW - HYDROSILYLATION

KW - X-RAY-STRUCTURE

KW - CRYSTAL-STRUCTURES

KW - ISONITRILES

KW - ALKYNES

KW - METAL COMPLEXES

KW - COLOR

KW - EMISSION

KW - PALLADIUM(II)

KW - CATALYSTS

UR - http://www.scopus.com/inward/record.url?scp=85051229975&partnerID=8YFLogxK

UR - https://elibrary.ru/item.asp?id=35715359

U2 - 10.1134/S107036321806021X

DO - 10.1134/S107036321806021X

M3 - Article

VL - 88

SP - 1180

EP - 1187

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 6

M1 - 8

ER -

ID: 28442723