DOI

Phosphine isocyanide complexes cis-[PtCl 2(CNMes)(P)] with mesitylisocyanide and phoshine ligands were synthesized in yields of 92‒98%. The products were characterized by mass spectrometry, IR and 1H NMR, COSY, NOESY, HSQC, and HMBC spectroscopy, and X-ray diffraction analysis. The solid-state and solution structures of the complexes and their stability in isomerization and ligand disproportionation reactions were studied.

Original languageEnglish
Article number8
Pages (from-to)1180-1187
Number of pages8
JournalRussian Journal of General Chemistry
Volume88
Issue number6
DOIs
StatePublished - Jun 2018

    Scopus subject areas

  • Inorganic Chemistry
  • Chemistry(all)

    Research areas

  • isocyanides, phosphines, platinum complexes, HYDROSILYLATION, X-RAY-STRUCTURE, CRYSTAL-STRUCTURES, ISONITRILES, ALKYNES, METAL COMPLEXES, COLOR, EMISSION, PALLADIUM(II), CATALYSTS

ID: 28442723