Research output: Contribution to journal › Article › peer-review
Synthesis of [99Tc(CO)6]+ Cation under Ambient Conditions. / Sakhonenkova, Anna P.; Slastihina, Polina V.; Sidorenko, Georgii V.; Tyupina, Margarita Yu; Miroslavov, Alexander E.
In: ChemistrySelect, Vol. 7, No. 15, e202201128, 21.04.2022.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Synthesis of [99Tc(CO)6]+ Cation under Ambient Conditions
AU - Sakhonenkova, Anna P.
AU - Slastihina, Polina V.
AU - Sidorenko, Georgii V.
AU - Tyupina, Margarita Yu
AU - Miroslavov, Alexander E.
PY - 2022/4/21
Y1 - 2022/4/21
N2 - Technetium(I) and rhenium(I) hexacarbonyl cations were prepared for the first time at atmospheric pressure and room temperature by treatment of dichloromethane or chloroform solutions of [99TcBr(CO)5] and [ReCl(CO)5] with carbon monoxide in the presence of dry aluminum trichloride. The yield was 17.0 % and 3.1 %, respectively.
AB - Technetium(I) and rhenium(I) hexacarbonyl cations were prepared for the first time at atmospheric pressure and room temperature by treatment of dichloromethane or chloroform solutions of [99TcBr(CO)5] and [ReCl(CO)5] with carbon monoxide in the presence of dry aluminum trichloride. The yield was 17.0 % and 3.1 %, respectively.
KW - atmospheric pressure
KW - carbonyl ligands
KW - rhenium
KW - synthesis design
KW - technetium
KW - X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=85128568213&partnerID=8YFLogxK
U2 - 10.1002/slct.202201128
DO - 10.1002/slct.202201128
M3 - Article
AN - SCOPUS:85128568213
VL - 7
JO - ChemistrySelect
JF - ChemistrySelect
SN - 2365-6549
IS - 15
M1 - e202201128
ER -
ID: 102709723