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Synthesis of [99Tc(CO)6]+ Cation under Ambient Conditions. / Sakhonenkova, Anna P.; Slastihina, Polina V.; Sidorenko, Georgii V.; Tyupina, Margarita Yu; Miroslavov, Alexander E.

In: ChemistrySelect, Vol. 7, No. 15, e202201128, 21.04.2022.

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Sakhonenkova, Anna P. ; Slastihina, Polina V. ; Sidorenko, Georgii V. ; Tyupina, Margarita Yu ; Miroslavov, Alexander E. / Synthesis of [99Tc(CO)6]+ Cation under Ambient Conditions. In: ChemistrySelect. 2022 ; Vol. 7, No. 15.

BibTeX

@article{c48bd6a62ce24c1c95fc7681b14a2175,
title = "Synthesis of [99Tc(CO)6]+ Cation under Ambient Conditions",
abstract = "Technetium(I) and rhenium(I) hexacarbonyl cations were prepared for the first time at atmospheric pressure and room temperature by treatment of dichloromethane or chloroform solutions of [99TcBr(CO)5] and [ReCl(CO)5] with carbon monoxide in the presence of dry aluminum trichloride. The yield was 17.0 % and 3.1 %, respectively.",
keywords = "atmospheric pressure, carbonyl ligands, rhenium, synthesis design, technetium, X-ray diffraction",
author = "Sakhonenkova, {Anna P.} and Slastihina, {Polina V.} and Sidorenko, {Georgii V.} and Tyupina, {Margarita Yu} and Miroslavov, {Alexander E.}",
year = "2022",
month = apr,
day = "21",
doi = "10.1002/slct.202201128",
language = "English",
volume = "7",
journal = "ChemistrySelect",
issn = "2365-6549",
publisher = "Wiley-Blackwell",
number = "15",

}

RIS

TY - JOUR

T1 - Synthesis of [99Tc(CO)6]+ Cation under Ambient Conditions

AU - Sakhonenkova, Anna P.

AU - Slastihina, Polina V.

AU - Sidorenko, Georgii V.

AU - Tyupina, Margarita Yu

AU - Miroslavov, Alexander E.

PY - 2022/4/21

Y1 - 2022/4/21

N2 - Technetium(I) and rhenium(I) hexacarbonyl cations were prepared for the first time at atmospheric pressure and room temperature by treatment of dichloromethane or chloroform solutions of [99TcBr(CO)5] and [ReCl(CO)5] with carbon monoxide in the presence of dry aluminum trichloride. The yield was 17.0 % and 3.1 %, respectively.

AB - Technetium(I) and rhenium(I) hexacarbonyl cations were prepared for the first time at atmospheric pressure and room temperature by treatment of dichloromethane or chloroform solutions of [99TcBr(CO)5] and [ReCl(CO)5] with carbon monoxide in the presence of dry aluminum trichloride. The yield was 17.0 % and 3.1 %, respectively.

KW - atmospheric pressure

KW - carbonyl ligands

KW - rhenium

KW - synthesis design

KW - technetium

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=85128568213&partnerID=8YFLogxK

U2 - 10.1002/slct.202201128

DO - 10.1002/slct.202201128

M3 - Article

AN - SCOPUS:85128568213

VL - 7

JO - ChemistrySelect

JF - ChemistrySelect

SN - 2365-6549

IS - 15

M1 - e202201128

ER -

ID: 102709723