Technetium(I) and rhenium(I) hexacarbonyl cations were prepared for the first time at atmospheric pressure and room temperature by treatment of dichloromethane or chloroform solutions of [99TcBr(CO)5] and [ReCl(CO)5] with carbon monoxide in the presence of dry aluminum trichloride. The yield was 17.0 % and 3.1 %, respectively.
Translated title of the contributionСинтез катиона [99Tc(CO)6]+ при атмосферном давлении
Original languageEnglish
Article numbere202201128
Issue number15
StatePublished - 21 Apr 2022

    Research areas

  • atmospheric pressure, carbonyl ligands, rhenium, synthesis design, technetium, X-ray diffraction

ID: 102709723