Research output: Contribution to journal › Article › peer-review
Synthesis of 2-Mono- and 2,2-Bis[2-(1H-tetrazol-5-yl)ethyl] Derivatives of Dipterocarpol. / Rodionov, E I; Kovaleva, A A; Зорина, Алла Дмитриевна; Старова, Галина Леонидовна; Трифонов, Ростислав Евгеньевич.
In: Russian Journal of Organic Chemistry, Vol. 54, No. 3, 03.2018, p. 485-489.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Synthesis of 2-Mono- and 2,2-Bis[2-(1H-tetrazol-5-yl)ethyl] Derivatives of Dipterocarpol
AU - Rodionov, E I
AU - Kovaleva, A A
AU - Зорина, Алла Дмитриевна
AU - Старова, Галина Леонидовна
AU - Трифонов, Ростислав Евгеньевич
N1 - Funding Information: This study was performed under financial support by the Russian Foundation for Basic Research (project no. 17-04-00981-a).
PY - 2018/3
Y1 - 2018/3
N2 - The azidation of 2,2-bis(2-cyanoethyl)-20-hydroxydammar-24-en-3-one afforded new tetrazole derivatives of natural dipterocarpol, 2-(2-cyanoethyl)-2-[2-(1H-tetrazol-5-yl)ethyl]-20-hydroxydammar-24-en- 3-ones, 2,2-bis[2-(1H-tetrazol-5-yl)ethyl]-20-hydroxydammar-24-en-3-one, and 2,2-bis[2-(1H-tetrazol-5-yl)- ethyl]-3-oxo-25,26,27-trinordammaran-(20S),24-olide. The structure of the final and intermediate products was determined by NMR spectroscopy and X-ray analysis.
AB - The azidation of 2,2-bis(2-cyanoethyl)-20-hydroxydammar-24-en-3-one afforded new tetrazole derivatives of natural dipterocarpol, 2-(2-cyanoethyl)-2-[2-(1H-tetrazol-5-yl)ethyl]-20-hydroxydammar-24-en- 3-ones, 2,2-bis[2-(1H-tetrazol-5-yl)ethyl]-20-hydroxydammar-24-en-3-one, and 2,2-bis[2-(1H-tetrazol-5-yl)- ethyl]-3-oxo-25,26,27-trinordammaran-(20S),24-olide. The structure of the final and intermediate products was determined by NMR spectroscopy and X-ray analysis.
KW - ACID
KW - CHEMISTRY
KW - CYANOETHYL DERIVATIVES
KW - TRITERPENOIDS
UR - http://www.scopus.com/inward/record.url?scp=85048116402&partnerID=8YFLogxK
UR - http://link.springer.com/10.1134/S107042801803017X
UR - http://www.mendeley.com/research/synthesis-2mono-22bis21htetrazol5ylethyl-derivatives-dipterocarpol
U2 - 10.1134/S107042801803017X
DO - 10.1134/S107042801803017X
M3 - Article
VL - 54
SP - 485
EP - 489
JO - Russian Journal of Organic Chemistry
JF - Russian Journal of Organic Chemistry
SN - 1070-4280
IS - 3
ER -
ID: 35404325