Synthesis and Study of the Structure of Palladium(II) Acyclic Diaminocarbene Complexes Containing a 1,2,4-Oxadiazole Moiety

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Synthesis and Study of the Structure of Palladium(II) Acyclic Diaminocarbene Complexes Containing a 1,2,4-Oxadiazole Moiety. / Baikov, S. V.; Trukhanova, Yu A.; Tarasenko, M. V.; Kinzhalov, M. A.

In: Russian Journal of General Chemistry, Vol. 90, No. 10, 10.2020, p. 1892-1900.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{07929539a69046088811867c470def15,

title = "Synthesis and Study of the Structure of Palladium(II) Acyclic Diaminocarbene Complexes Containing a 1,2,4-Oxadiazole Moiety",

abstract = "Abstract: The reaction of anilines containing a 1,2,4-oxadiazole moiety with thebis(xylylisocyanide) Pd(II) complex leads to the formation of acyclicdiaminocarbene complexes. The oxadiazole ring is not involved in the reaction.Composition and structure of the obtained complexes have been confirmed by meansof mass spectrometry, NMR spectroscopy, and single-crystal X-ray diffractionanalysis.",

keywords = "acyclic diaminocarbene palladium complexes, isocyanide ligands, oxadiazoles, π–π-stacking",

author = "Baikov, {S. V.} and Trukhanova, {Yu A.} and Tarasenko, {M. V.} and Kinzhalov, {M. A.}",

note = "Funding Information: This study was financially supported by the Council for Grants of the President of Russian Federation (grant MK-1074.2020.3) and performed using the equipment of Resource Centers of St. Petersburg State University: “Magnetic Resonance Methods” and “X-ray Diffraction Methods.” Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2020",

month = oct,

doi = "10.1134/S1070363220100126",

language = "English",

volume = "90",

pages = "1892--1900",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "10",

}

RIS

TY - JOUR

T1 - Synthesis and Study of the Structure of Palladium(II) Acyclic Diaminocarbene Complexes Containing a 1,2,4-Oxadiazole Moiety

AU - Baikov, S. V.

AU - Trukhanova, Yu A.

AU - Tarasenko, M. V.

AU - Kinzhalov, M. A.

N1 - Funding Information: This study was financially supported by the Council for Grants of the President of Russian Federation (grant MK-1074.2020.3) and performed using the equipment of Resource Centers of St. Petersburg State University: “Magnetic Resonance Methods” and “X-ray Diffraction Methods.” Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/10

Y1 - 2020/10

N2 - Abstract: The reaction of anilines containing a 1,2,4-oxadiazole moiety with thebis(xylylisocyanide) Pd(II) complex leads to the formation of acyclicdiaminocarbene complexes. The oxadiazole ring is not involved in the reaction.Composition and structure of the obtained complexes have been confirmed by meansof mass spectrometry, NMR spectroscopy, and single-crystal X-ray diffractionanalysis.

AB - Abstract: The reaction of anilines containing a 1,2,4-oxadiazole moiety with thebis(xylylisocyanide) Pd(II) complex leads to the formation of acyclicdiaminocarbene complexes. The oxadiazole ring is not involved in the reaction.Composition and structure of the obtained complexes have been confirmed by meansof mass spectrometry, NMR spectroscopy, and single-crystal X-ray diffractionanalysis.

KW - acyclic diaminocarbene palladium complexes

KW - isocyanide ligands

KW - oxadiazoles

KW - π–π-stacking

UR - http://www.scopus.com/inward/record.url?scp=85096164154&partnerID=8YFLogxK

U2 - 10.1134/S1070363220100126

DO - 10.1134/S1070363220100126

M3 - Article

AN - SCOPUS:85096164154

VL - 90

SP - 1892

EP - 1900

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 10

ER -

ID: 72621892