Synthesis and Study of the Structure of Palladium(II) Acyclic Diaminocarbene Complexes Containing a 1,2,4-Oxadiazole Moiety

Research output: Contribution to journal › Article › peer-review

Department of Physical Organic Chemistry

DOI

https://doi.org/10.1134/S1070363220100126
Final published version

S. V. Baikov
Yu A. Trukhanova
M. V. Tarasenko
M. A. Kinzhalov

Abstract: The reaction of anilines containing a 1,2,4-oxadiazole moiety with thebis(xylylisocyanide) Pd(II) complex leads to the formation of acyclicdiaminocarbene complexes. The oxadiazole ring is not involved in the reaction.Composition and structure of the obtained complexes have been confirmed by meansof mass spectrometry, NMR spectroscopy, and single-crystal X-ray diffractionanalysis.

Original language	English
Pages (from-to)	1892-1900
Number of pages	9
Journal	Russian Journal of General Chemistry
Volume	90
Issue number	10
DOIs	https://doi.org/10.1134/S1070363220100126
State	Published - Oct 2020

Scopus subject areas

Chemistry(all)

Research areas

acyclic diaminocarbene palladium complexes, isocyanide ligands, oxadiazoles, π–π-stacking

ID: 72621892