Synthesis and Structure of Cobalt(III) Complex with Cyanomethylene and N,N′-Ethylenebis(3-methylsalicylideneiminate)

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Synthesis and Structure of Cobalt(III) Complex with Cyanomethylene and N,N′-Ethylenebis(3-methylsalicylideneiminate). / Novozhilova, M. V.; Spiridonova, D. V.; Karushev, M. P.; Timonov, A. M.

In: Russian Journal of General Chemistry, Vol. 92, No. 2, 01.02.2022, p. 261-264.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{9dc63038a29148739421d5fb20ee7ac9,

title = "Synthesis and Structure of Cobalt(III) Complex with Cyanomethylene and N,N′-Ethylenebis(3-methylsalicylideneiminate)",

abstract = "The new complex [Co-III(3-CH(3)Salen)(CH2CN)]center dot CH3CN was synthesized and its crystal structure was determined by the X-ray diffraction analysis. The cyanomethylene ligand is bound to the metallocenter by a Co-C bond. In the crystalline state, an organometallic polymer structure is formed, in which metal atoms are interconnected by cyanomethylene bridges.",

keywords = "cobalt complexes with metal‒carbon bond, cobalt(III) complexes, electron-donor substituents, organometallic polymer, salene-type Schiff bases, SALEN COMPLEXES, cobalt complexes with metal-carbon bond",

author = "Novozhilova, {M. V.} and Spiridonova, {D. V.} and Karushev, {M. P.} and Timonov, {A. M.}",

note = "Publisher Copyright: {\textcopyright} 2022, Pleiades Publishing, Ltd.",

year = "2022",

month = feb,

day = "1",

doi = "10.1134/s1070363222020165",

language = "English",

volume = "92",

pages = "261--264",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "2",

}

RIS

TY - JOUR

T1 - Synthesis and Structure of Cobalt(III) Complex with Cyanomethylene and N,N′-Ethylenebis(3-methylsalicylideneiminate)

AU - Novozhilova, M. V.

AU - Spiridonova, D. V.

AU - Karushev, M. P.

AU - Timonov, A. M.

PY - 2022/2/1

Y1 - 2022/2/1

N2 - The new complex [Co-III(3-CH(3)Salen)(CH2CN)]center dot CH3CN was synthesized and its crystal structure was determined by the X-ray diffraction analysis. The cyanomethylene ligand is bound to the metallocenter by a Co-C bond. In the crystalline state, an organometallic polymer structure is formed, in which metal atoms are interconnected by cyanomethylene bridges.

AB - The new complex [Co-III(3-CH(3)Salen)(CH2CN)]center dot CH3CN was synthesized and its crystal structure was determined by the X-ray diffraction analysis. The cyanomethylene ligand is bound to the metallocenter by a Co-C bond. In the crystalline state, an organometallic polymer structure is formed, in which metal atoms are interconnected by cyanomethylene bridges.

KW - cobalt complexes with metal‒carbon bond

KW - cobalt(III) complexes

KW - electron-donor substituents

KW - organometallic polymer

KW - salene-type Schiff bases

KW - SALEN COMPLEXES

KW - cobalt complexes with metal-carbon bond

UR - http://www.scopus.com/inward/record.url?scp=85126244362&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/1f581e1b-660b-316e-bbcf-66196884963c/

U2 - 10.1134/s1070363222020165

DO - 10.1134/s1070363222020165

M3 - Article

AN - SCOPUS:85126244362

VL - 92

SP - 261

EP - 264

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 2

ER -

ID: 93999891