Synthesis and Structure of Cobalt(III) Complex with Cyanomethylene and N,N′-Ethylenebis(3-methylsalicylideneiminate)

Research output: Contribution to journal › Article › peer-review

DOI

https://doi.org/10.1134/s1070363222020165
Final published version

M. V. Novozhilova
D. V. Spiridonova
M. P. Karushev
A. M. Timonov

The new complex [Co-III(3-CH(3)Salen)(CH2CN)]center dot CH3CN was synthesized and its crystal structure was determined by the X-ray diffraction analysis. The cyanomethylene ligand is bound to the metallocenter by a Co-C bond. In the crystalline state, an organometallic polymer structure is formed, in which metal atoms are interconnected by cyanomethylene bridges.

Original language	English
Pages (from-to)	261-264
Number of pages	4
Journal	Russian Journal of General Chemistry
Volume	92
Issue number	2
DOIs	https://doi.org/10.1134/s1070363222020165
State	Published - 1 Feb 2022

Scopus subject areas

Chemistry(all)

Research areas

cobalt complexes with metal‒carbon bond, cobalt(III) complexes, electron-donor substituents, organometallic polymer, salene-type Schiff bases, SALEN COMPLEXES, cobalt complexes with metal-carbon bond

ID: 93999891