Supramolecular Bromoantimonate(V) Polybromide (2,6-BrPyH)3[SbBr6]{(Br2)Br}

Supramolecular Bromoantimonate(V) Polybromide (2,6-BrPyH)₃[SbBr₆]{(Br₂)Br} · 2H₂O: Specific Features of Halogen···Halogen Contacts in the Crystal Structure

Research output: Contribution to journal › Article › peer-review

Institute of Chemistry

DOI

https://doi.org/10.1134/S1070328420040016
Final published version

M. A. Bondarenko
S. A. Adonin
A. S. Novikov
M. N. Sokolov
V. P. Fedin

Abstract: The reaction of a solution of Sb₂O₃ in HBr in the presence of Br₂ with a solution of 2,6-dibromopyridine (2,6-BrPy) in HBr affords supramolecular bromoantimonate polybromide (2,6-BrPy)₃[SbBr₆]-{(Br₂)Br} · 2H₂O (I). The structure of compound I is determined by X-ray structure analysis (СIF file CCDC no. 1962867). The energies of noncovalent Br···Br interactions in the solid state are estimated by quantum-chemical calculations.

Original language	English
Pages (from-to)	302-307
Number of pages	6
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	46
Issue number	5
DOIs	https://doi.org/10.1134/S1070328420040016
State	Published - 1 May 2020

Research areas

antimony, halide complexes, halogen bond, noncovalent interactions, quantum-chemical calculations, ANIONS, INTERPLAY, ENERGY, NONABROMOANTIMONATE(V), NONCOVALENT INTERACTIONS, BOND, BROMIDE COMPLEXES

Scopus subject areas

Chemical Engineering(all)
Chemistry(all)

ID: 53561875