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Structure of the Product of 1,3,5,7-Tetra-tert-butyloctahydro-1H,4аH-imidazo[4′,5′:5,6]dioxino[2,3-d]imidazole Cocrystallization with 1,3-Di-tert-butylimidazol-2-one and 1,3-Di-tert-butylimidazolin-2-ylidene. / Chernysheva, A. M.; Virovets, A. V.; Peresypkina, E. V.; Timoshkin, A. Yu.

In: Russian Journal of General Chemistry, Vol. 90, No. 9, 01.09.2020, p. 1625-1629.

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@article{2a3071b34a05451c8f68cb32bafb0565,
title = "Structure of the Product of 1,3,5,7-Tetra-tert-butyloctahydro-1H,4аH-imidazo[4′,5′:5,6]dioxino[2,3-d]imidazole Cocrystallization with 1,3-Di-tert-butylimidazol-2-one and 1,3-Di-tert-butylimidazolin-2-ylidene",
abstract = "Abstract: Structure of the product of imidazolidine (1,3,5,7-tetra-tert-butyloctahydro-1H,4аH-imidazo[4ʹ,5ʹ:5,6]dioxino[2,3-d]imidazole) ether cocrytallization with 1,3-di-tert-butylimidazol-2-one and 1,3-di-tert-butylimidazolin-2-ylidene was established by single crystal X-ray diffraction. The co-crystal is the product of the oxidation-hydrolysis of the 1,3-di-tert-butylimidazolin-2-ylidene complex with AlH3.",
keywords = "imidazol-2-one, imidazolidine, imidazolin-2-ylidene, N-heterocyclic carbene, reactivity, OXIDATION, REACTIVITY, NHC, N-HETEROCYCLIC CARBENES, DERIVATIVES",
author = "Chernysheva, {A. M.} and Virovets, {A. V.} and Peresypkina, {E. V.} and Timoshkin, {A. Yu}",
note = "Funding Information: This work was carried out with the financial support of St. Petersburg State University (grant SPbSU-DFG 12.65.44.2017, enterprise 6 12.42.719.2017 and 28875246). Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = sep,
day = "1",
doi = "10.1134/S1070363220090066",
language = "English",
volume = "90",
pages = "1625--1629",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "9",

}

RIS

TY - JOUR

T1 - Structure of the Product of 1,3,5,7-Tetra-tert-butyloctahydro-1H,4аH-imidazo[4′,5′:5,6]dioxino[2,3-d]imidazole Cocrystallization with 1,3-Di-tert-butylimidazol-2-one and 1,3-Di-tert-butylimidazolin-2-ylidene

AU - Chernysheva, A. M.

AU - Virovets, A. V.

AU - Peresypkina, E. V.

AU - Timoshkin, A. Yu

N1 - Funding Information: This work was carried out with the financial support of St. Petersburg State University (grant SPbSU-DFG 12.65.44.2017, enterprise 6 12.42.719.2017 and 28875246). Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/9/1

Y1 - 2020/9/1

N2 - Abstract: Structure of the product of imidazolidine (1,3,5,7-tetra-tert-butyloctahydro-1H,4аH-imidazo[4ʹ,5ʹ:5,6]dioxino[2,3-d]imidazole) ether cocrytallization with 1,3-di-tert-butylimidazol-2-one and 1,3-di-tert-butylimidazolin-2-ylidene was established by single crystal X-ray diffraction. The co-crystal is the product of the oxidation-hydrolysis of the 1,3-di-tert-butylimidazolin-2-ylidene complex with AlH3.

AB - Abstract: Structure of the product of imidazolidine (1,3,5,7-tetra-tert-butyloctahydro-1H,4аH-imidazo[4ʹ,5ʹ:5,6]dioxino[2,3-d]imidazole) ether cocrytallization with 1,3-di-tert-butylimidazol-2-one and 1,3-di-tert-butylimidazolin-2-ylidene was established by single crystal X-ray diffraction. The co-crystal is the product of the oxidation-hydrolysis of the 1,3-di-tert-butylimidazolin-2-ylidene complex with AlH3.

KW - imidazol-2-one

KW - imidazolidine

KW - imidazolin-2-ylidene

KW - N-heterocyclic carbene

KW - reactivity

KW - OXIDATION

KW - REACTIVITY

KW - NHC

KW - N-HETEROCYCLIC CARBENES

KW - DERIVATIVES

UR - http://www.scopus.com/inward/record.url?scp=85092355858&partnerID=8YFLogxK

U2 - 10.1134/S1070363220090066

DO - 10.1134/S1070363220090066

M3 - Article

AN - SCOPUS:85092355858

VL - 90

SP - 1625

EP - 1629

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 9

ER -

ID: 70092011