Structure of the Product of 1,3,5,7-Tetra-tert-butyloctahydro-1H,4аH-imidazo[4′,5′:5,6]dioxino[2,3-d]imidazole Cocrystallization with 1,3-Di-tert-butylimidazol-2-one and 1,3-Di-tert-butylimidazolin-2-ylidene

Research output: Contribution to journal › Article › peer-review

DOI

https://doi.org/10.1134/S1070363220090066
Final published version

A. M. Chernysheva
A. V. Virovets
E. V. Peresypkina
A. Yu Timoshkin

Abstract: Structure of the product of imidazolidine (1,3,5,7-tetra-tert-butyloctahydro-1H,4аH-imidazo[4ʹ,5ʹ:5,6]dioxino[2,3-d]imidazole) ether cocrytallization with 1,3-di-tert-butylimidazol-2-one and 1,3-di-tert-butylimidazolin-2-ylidene was established by single crystal X-ray diffraction. The co-crystal is the product of the oxidation-hydrolysis of the 1,3-di-tert-butylimidazolin-2-ylidene complex with AlH₃.

Original language	English
Pages (from-to)	1625-1629
Number of pages	5
Journal	Russian Journal of General Chemistry
Volume	90
Issue number	9
DOIs	https://doi.org/10.1134/S1070363220090066
State	Published - 1 Sep 2020

Scopus subject areas

Chemistry(all)

Research areas

imidazol-2-one, imidazolidine, imidazolin-2-ylidene, N-heterocyclic carbene, reactivity, OXIDATION, REACTIVITY, NHC, N-HETEROCYCLIC CARBENES, DERIVATIVES

ID: 70092011