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Structure and Luminescent Properties of Glasses in the GeS2-Ga2S3-Sb2S3:Pr3+ System. / Tverjanovich, Andrey; Tveryanovich, Yurii S.; Shahbazova, Christina.

In: Materials, Vol. 16, No. 13, 4672, 28.06.2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Tverjanovich, A, Tveryanovich, YS & Shahbazova, C 2023, 'Structure and Luminescent Properties of Glasses in the GeS2-Ga2S3-Sb2S3:Pr3+ System', Materials, vol. 16, no. 13, 4672. https://doi.org/10.3390/ma16134672

APA

Tverjanovich, A., Tveryanovich, Y. S., & Shahbazova, C. (2023). Structure and Luminescent Properties of Glasses in the GeS2-Ga2S3-Sb2S3:Pr3+ System. Materials, 16(13), [4672]. https://doi.org/10.3390/ma16134672

Vancouver

Tverjanovich A, Tveryanovich YS, Shahbazova C. Structure and Luminescent Properties of Glasses in the GeS2-Ga2S3-Sb2S3:Pr3+ System. Materials. 2023 Jun 28;16(13). 4672. https://doi.org/10.3390/ma16134672

Author

Tverjanovich, Andrey ; Tveryanovich, Yurii S. ; Shahbazova, Christina. / Structure and Luminescent Properties of Glasses in the GeS2-Ga2S3-Sb2S3:Pr3+ System. In: Materials. 2023 ; Vol. 16, No. 13.

BibTeX

@article{cb2285abb32f41a7b671cd00a8c039c3,
title = "Structure and Luminescent Properties of Glasses in the GeS2-Ga2S3-Sb2S3:Pr3+ System",
abstract = "The physicochemical, optical, and luminescent properties and structures of glasses of the Ga 2S 3-GeS 2-Sb 2S 3:Pr system have been studied in a wide range of concentrations of the main components in order to reveal their correlation with the composition. According to the calculations using the Judd-Ofelt theory, glasses with a high content of Sb 2S 3 should provide the highest luminescence efficiency of Pr 3+ ions. However, this result is leveled by enhancing the concentration quenching effect, followed by an increase of the Sb 2S 3 content in the glasses. The introduction of Pr leads to a significant increase in the fraction of Sb-Sb, Sb-Ge, Ge-Ge bonds in glasses enriched with Sb 2S 3 and GeS 2. In the cases of the glasses enriched with Ga 2S 3, this effect was not observed, apparently because Ga promotes the formation of three-coordinated sulfur atoms. ",
author = "Andrey Tverjanovich and Tveryanovich, {Yurii S.} and Christina Shahbazova",
year = "2023",
month = jun,
day = "28",
doi = "10.3390/ma16134672",
language = "English",
volume = "16",
journal = "Materials",
issn = "1996-1944",
publisher = "MDPI AG",
number = "13",

}

RIS

TY - JOUR

T1 - Structure and Luminescent Properties of Glasses in the GeS2-Ga2S3-Sb2S3:Pr3+ System

AU - Tverjanovich, Andrey

AU - Tveryanovich, Yurii S.

AU - Shahbazova, Christina

PY - 2023/6/28

Y1 - 2023/6/28

N2 - The physicochemical, optical, and luminescent properties and structures of glasses of the Ga 2S 3-GeS 2-Sb 2S 3:Pr system have been studied in a wide range of concentrations of the main components in order to reveal their correlation with the composition. According to the calculations using the Judd-Ofelt theory, glasses with a high content of Sb 2S 3 should provide the highest luminescence efficiency of Pr 3+ ions. However, this result is leveled by enhancing the concentration quenching effect, followed by an increase of the Sb 2S 3 content in the glasses. The introduction of Pr leads to a significant increase in the fraction of Sb-Sb, Sb-Ge, Ge-Ge bonds in glasses enriched with Sb 2S 3 and GeS 2. In the cases of the glasses enriched with Ga 2S 3, this effect was not observed, apparently because Ga promotes the formation of three-coordinated sulfur atoms.

AB - The physicochemical, optical, and luminescent properties and structures of glasses of the Ga 2S 3-GeS 2-Sb 2S 3:Pr system have been studied in a wide range of concentrations of the main components in order to reveal their correlation with the composition. According to the calculations using the Judd-Ofelt theory, glasses with a high content of Sb 2S 3 should provide the highest luminescence efficiency of Pr 3+ ions. However, this result is leveled by enhancing the concentration quenching effect, followed by an increase of the Sb 2S 3 content in the glasses. The introduction of Pr leads to a significant increase in the fraction of Sb-Sb, Sb-Ge, Ge-Ge bonds in glasses enriched with Sb 2S 3 and GeS 2. In the cases of the glasses enriched with Ga 2S 3, this effect was not observed, apparently because Ga promotes the formation of three-coordinated sulfur atoms.

UR - https://www.mendeley.com/catalogue/af4453c7-7948-3bb6-82c4-34b43c9bce31/

U2 - 10.3390/ma16134672

DO - 10.3390/ma16134672

M3 - Article

C2 - 37444986

VL - 16

JO - Materials

JF - Materials

SN - 1996-1944

IS - 13

M1 - 4672

ER -

ID: 107449809