DOI

Imidazoline-fused [1,4]oxazepines (prepared in two simple steps from methyl 2-hydroxyaroates, ethylene diamine and bis-electrophilic aromatics) undergo a facile, good-yielding hydrolytic imidazoline ring expansion (HIRE) upon N-alkylation and treatment with aqueous K2CO3. The resulting arene-fused ten-membered lactams significantly add to the contemporary arsenal of small-molecule scaffolds where medium-sized ring systems are severely underrepresented.
Original languageEnglish
Pages (from-to)2906-2909
Number of pages4
JournalOrganic and Biomolecular Chemistry
Issue number15
DOIs
StatePublished - 2017

ID: 9277718