Spectral manifestation of resonance interactions in the fundamental and overtone regions of the XH-group bending vibration of the trifluoropropyne-amine complex

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Spectral manifestation of resonance interactions in the fundamental and overtone regions of the XH-group bending vibration of the trifluoropropyne-amine complex. / Blagoveshchenskii, N. A.; Kolomiitsova, T. D.; Melikova, S. M.; Shchepkin, D. N.

In: Optics and Spectroscopy (English translation of Optika i Spektroskopiya), Vol. 76, No. 5, 05.1994, p. 655-660.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{c4fb3da2f9454b16b9a8d16d20159255,

title = "Spectral manifestation of resonance interactions in the fundamental and overtone regions of the XH-group bending vibration of the trifluoropropyne-amine complex",

abstract = "IR spectra of the CF3CCH...N(CD3)3 complex dissolved in liquid argon were studied in large optical paths ({\=l}2 m). All relatively broad bands (Δ1/2≥30 cm-1) were ascribed to CH vibrations and their shapes were interpreted within the framework of a unified approach to the interaction of CH vibrations with low-frequency intermolecular modes. Occurrence of a triple resonance in the overtone region lends support to the conclusion that the Evans hole in the complicated contour of the v7 CH bending mode results from the Fermi resonance v7 ≈v8+v10 in the CF3CCH molecule.",

author = "Blagoveshchenskii, {N. A.} and Kolomiitsova, {T. D.} and Melikova, {S. M.} and Shchepkin, {D. N.}",

year = "1994",

month = may,

language = "English",

volume = "76",

pages = "655--660",

journal = "OPTICS AND SPECTROSCOPY",

issn = "0030-400X",

publisher = "Pleiades Publishing",

number = "5",

}

RIS

TY - JOUR

T1 - Spectral manifestation of resonance interactions in the fundamental and overtone regions of the XH-group bending vibration of the trifluoropropyne-amine complex

AU - Blagoveshchenskii, N. A.

AU - Kolomiitsova, T. D.

AU - Melikova, S. M.

AU - Shchepkin, D. N.

PY - 1994/5

Y1 - 1994/5

N2 - IR spectra of the CF3CCH...N(CD3)3 complex dissolved in liquid argon were studied in large optical paths (l̄2 m). All relatively broad bands (Δ1/2≥30 cm-1) were ascribed to CH vibrations and their shapes were interpreted within the framework of a unified approach to the interaction of CH vibrations with low-frequency intermolecular modes. Occurrence of a triple resonance in the overtone region lends support to the conclusion that the Evans hole in the complicated contour of the v7 CH bending mode results from the Fermi resonance v7 ≈v8+v10 in the CF3CCH molecule.

AB - IR spectra of the CF3CCH...N(CD3)3 complex dissolved in liquid argon were studied in large optical paths (l̄2 m). All relatively broad bands (Δ1/2≥30 cm-1) were ascribed to CH vibrations and their shapes were interpreted within the framework of a unified approach to the interaction of CH vibrations with low-frequency intermolecular modes. Occurrence of a triple resonance in the overtone region lends support to the conclusion that the Evans hole in the complicated contour of the v7 CH bending mode results from the Fermi resonance v7 ≈v8+v10 in the CF3CCH molecule.

UR - http://www.scopus.com/inward/record.url?scp=0028428413&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0028428413

VL - 76

SP - 655

EP - 660

JO - OPTICS AND SPECTROSCOPY

JF - OPTICS AND SPECTROSCOPY

SN - 0030-400X

IS - 5

ER -

ID: 90572809