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Solubility of d-Element Salts in Organic and Aqueous-Organic Solvents : VII. Structure of Nickel Chloride Solvatocomplexes. / Bogachev, N. A.; Tsyrul’nikov, N. A.; Makarova, A. A.; Tolmachev, M. V.; Starova, G. L.; Skripkin, M. Yu; Nikol’skii, A. B.

In: Russian Journal of General Chemistry, Vol. 89, No. 5, 01.05.2019, p. 859-864.

Research output: Contribution to journal › Article › peer-review

Harvard

Bogachev, NA, Tsyrul’nikov, NA, Makarova, AA, Tolmachev, MV, Starova, GL, Skripkin, MY & Nikol’skii, AB 2019, 'Solubility of d-Element Salts in Organic and Aqueous-Organic Solvents: VII. Structure of Nickel Chloride Solvatocomplexes', Russian Journal of General Chemistry, vol. 89, no. 5, pp. 859-864. https://doi.org/10.1134/S1070363219050013

APA

Bogachev, N. A., Tsyrul’nikov, N. A., Makarova, A. A., Tolmachev, M. V., Starova, G. L., Skripkin, M. Y., & Nikol’skii, A. B. (2019). Solubility of d-Element Salts in Organic and Aqueous-Organic Solvents: VII. Structure of Nickel Chloride Solvatocomplexes. Russian Journal of General Chemistry, 89(5), 859-864. https://doi.org/10.1134/S1070363219050013

Vancouver

Bogachev NA, Tsyrul’nikov NA, Makarova AA, Tolmachev MV, Starova GL, Skripkin MY et al. Solubility of d-Element Salts in Organic and Aqueous-Organic Solvents: VII. Structure of Nickel Chloride Solvatocomplexes. Russian Journal of General Chemistry. 2019 May 1;89(5):859-864. https://doi.org/10.1134/S1070363219050013

Author

Bogachev, N. A. ; Tsyrul’nikov, N. A. ; Makarova, A. A. ; Tolmachev, M. V. ; Starova, G. L. ; Skripkin, M. Yu ; Nikol’skii, A. B. / Solubility of d-Element Salts in Organic and Aqueous-Organic Solvents : VII. Structure of Nickel Chloride Solvatocomplexes. In: Russian Journal of General Chemistry. 2019 ; Vol. 89, No. 5. pp. 859-864.

BibTeX

@article{d443bbaf546f498ba961c89b75962204,
title = "Solubility of d-Element Salts in Organic and Aqueous-Organic Solvents: VII. Structure of Nickel Chloride Solvatocomplexes",
abstract = "Four complexes [Ni(DMA)2(H2O)4]Cl2·2H2O, [Ni(DMF)2(H2O)4]Cl2·2H2O, and [Ni(DMA)6][NiCl4], [Ni(DMF)2(H2O)2Cl2] were isolated from ternary water-organic saline systems containing nickel chloride and N, N-dimethylacetamide-water and N, N-dimethylformamide-water binary solvents. The obtained complexes were studied by X-ray structural analysis. The formation of hydrogen bonds between water molecules of the nickel ion solvate sphere, chloride ions, and non-coordinated water molecules located in the cavity of the crystal structure was detected.",
keywords = "hydrogen bonds, nickel chloride solvates, nickel complex compounds, ternary systems, LIGANDS, COMPLEXES, BROMIDE, AMIDES",
author = "Bogachev, {N. A.} and Tsyrul{\textquoteright}nikov, {N. A.} and Makarova, {A. A.} and Tolmachev, {M. V.} and Starova, {G. L.} and Skripkin, {M. Yu} and Nikol{\textquoteright}skii, {A. B.}",
year = "2019",
month = may,
day = "1",
doi = "10.1134/S1070363219050013",
language = "English",
volume = "89",
pages = "859--864",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "5",

}

RIS

TY - JOUR

T1 - Solubility of d-Element Salts in Organic and Aqueous-Organic Solvents

T2 - VII. Structure of Nickel Chloride Solvatocomplexes

AU - Bogachev, N. A.

AU - Tsyrul’nikov, N. A.

AU - Makarova, A. A.

AU - Tolmachev, M. V.

AU - Starova, G. L.

AU - Skripkin, M. Yu

AU - Nikol’skii, A. B.

PY - 2019/5/1

Y1 - 2019/5/1

N2 - Four complexes [Ni(DMA)2(H2O)4]Cl2·2H2O, [Ni(DMF)2(H2O)4]Cl2·2H2O, and [Ni(DMA)6][NiCl4], [Ni(DMF)2(H2O)2Cl2] were isolated from ternary water-organic saline systems containing nickel chloride and N, N-dimethylacetamide-water and N, N-dimethylformamide-water binary solvents. The obtained complexes were studied by X-ray structural analysis. The formation of hydrogen bonds between water molecules of the nickel ion solvate sphere, chloride ions, and non-coordinated water molecules located in the cavity of the crystal structure was detected.

AB - Four complexes [Ni(DMA)2(H2O)4]Cl2·2H2O, [Ni(DMF)2(H2O)4]Cl2·2H2O, and [Ni(DMA)6][NiCl4], [Ni(DMF)2(H2O)2Cl2] were isolated from ternary water-organic saline systems containing nickel chloride and N, N-dimethylacetamide-water and N, N-dimethylformamide-water binary solvents. The obtained complexes were studied by X-ray structural analysis. The formation of hydrogen bonds between water molecules of the nickel ion solvate sphere, chloride ions, and non-coordinated water molecules located in the cavity of the crystal structure was detected.

KW - hydrogen bonds

KW - nickel chloride solvates

KW - nickel complex compounds

KW - ternary systems

KW - LIGANDS

KW - COMPLEXES

KW - BROMIDE

KW - AMIDES

UR - http://www.scopus.com/inward/record.url?scp=85068035081&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/solubility-delement-salts-organic-aqueousorganic-solvents-vii-structure-nickel-chloride-solvatocompl

U2 - 10.1134/S1070363219050013

DO - 10.1134/S1070363219050013

M3 - Article

AN - SCOPUS:85068035081

VL - 89

SP - 859

EP - 864

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 5

ER -

ID: 45287101