Four complexes [Ni(DMA)2(H2O)4]Cl2·2H2O, [Ni(DMF)2(H2O)4]Cl2·2H2O, and [Ni(DMA)6][NiCl4], [Ni(DMF)2(H2O)2Cl2] were isolated from ternary water-organic saline systems containing nickel chloride and N, N-dimethylacetamide-water and N, N-dimethylformamide-water binary solvents. The obtained complexes were studied by X-ray structural analysis. The formation of hydrogen bonds between water molecules of the nickel ion solvate sphere, chloride ions, and non-coordinated water molecules located in the cavity of the crystal structure was detected.

Original languageEnglish
Pages (from-to)859-864
Number of pages6
JournalRussian Journal of General Chemistry
Volume89
Issue number5
DOIs
StatePublished - 1 May 2019

    Research areas

  • hydrogen bonds, nickel chloride solvates, nickel complex compounds, ternary systems, LIGANDS, COMPLEXES, BROMIDE, AMIDES

    Scopus subject areas

  • Chemistry(all)

ID: 45287101