Solid-liquid phase equilibria in the fullerenol-d-CuCl2-H 2O system at 25°C

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Solid-liquid phase equilibria in the fullerenol-d-CuCl₂-H ₂O system at 25°C. / Semenov, K. N.; Kanterman, I. G.; Charykov, N. A.; Murin, I. V.; Kritchenkov, A. S.

In: Russian Journal of Physical Chemistry A, Vol. 88, No. 6, 06.2014, p. 1073-1075.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{668e773601f64fcdb6d550e15e78fdf0,

title = "Solid-liquid phase equilibria in the fullerenol-d-CuCl2-H 2O system at 25°C",

abstract = "Solubility in the ternary fullerenol-d-CuCl2-H2O system at 25°C is studied by means of isothermal saturation in ampoules. It is established that the diagram consists of two branches corresponding to the crystallization of fullerenol-d crystallohydrate and copper(II) chloride dihydrate and contains a single non-variant eutonic point corresponding to the reciprocal saturation with both solid phases. The salting-in effect on the crystallization branch of CuCl2 · 2H2O and the salting-out effect on the crystallization branch of fullerenol-d is revealed.",

keywords = "copper(II) chloride, fullerenol, simple eutonics, solubility diagram, water",

author = "Semenov, {K. N.} and Kanterman, {I. G.} and Charykov, {N. A.} and Murin, {I. V.} and Kritchenkov, {A. S.}",

note = "Funding Information: ACKNOWLEDGMENTS This work was supported by the Russian Founda tion for Basic Research, project nos. 12 03 31380 mol_a and 11 08 00219 a; and by an RF Presidential Grant for the Support of Young Russian Scientists, project no. MK 3151.2013.3.",

year = "2014",

month = jun,

doi = "10.1134/S0036024414060272",

language = "English",

volume = "88",

pages = "1073--1075",

journal = "Russian Journal of Physical Chemistry A",

issn = "0036-0244",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "6",

}

RIS

TY - JOUR

T1 - Solid-liquid phase equilibria in the fullerenol-d-CuCl2-H 2O system at 25°C

AU - Semenov, K. N.

AU - Kanterman, I. G.

AU - Charykov, N. A.

AU - Murin, I. V.

AU - Kritchenkov, A. S.

N1 - Funding Information: ACKNOWLEDGMENTS This work was supported by the Russian Founda tion for Basic Research, project nos. 12 03 31380 mol_a and 11 08 00219 a; and by an RF Presidential Grant for the Support of Young Russian Scientists, project no. MK 3151.2013.3.

PY - 2014/6

Y1 - 2014/6

N2 - Solubility in the ternary fullerenol-d-CuCl2-H2O system at 25°C is studied by means of isothermal saturation in ampoules. It is established that the diagram consists of two branches corresponding to the crystallization of fullerenol-d crystallohydrate and copper(II) chloride dihydrate and contains a single non-variant eutonic point corresponding to the reciprocal saturation with both solid phases. The salting-in effect on the crystallization branch of CuCl2 · 2H2O and the salting-out effect on the crystallization branch of fullerenol-d is revealed.

AB - Solubility in the ternary fullerenol-d-CuCl2-H2O system at 25°C is studied by means of isothermal saturation in ampoules. It is established that the diagram consists of two branches corresponding to the crystallization of fullerenol-d crystallohydrate and copper(II) chloride dihydrate and contains a single non-variant eutonic point corresponding to the reciprocal saturation with both solid phases. The salting-in effect on the crystallization branch of CuCl2 · 2H2O and the salting-out effect on the crystallization branch of fullerenol-d is revealed.

KW - copper(II) chloride

KW - fullerenol

KW - simple eutonics

KW - solubility diagram

KW - water

UR - http://www.scopus.com/inward/record.url?scp=84901044177&partnerID=8YFLogxK

U2 - 10.1134/S0036024414060272

DO - 10.1134/S0036024414060272

M3 - Article

VL - 88

SP - 1073

EP - 1075

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

SN - 0036-0244

IS - 6

ER -

ID: 7008883