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Selective Synthesis of 2-Methylidenepyrrol-3-Ones from Diynones and Amines. / Pankova, Alena S.; Cherepanova, Nadezhda D.; Golubev, Pavel; Kuznetsov, Mikhail A.

In: Chemistry of Heterocyclic Compounds, Vol. 55, No. 7, 15.07.2019, p. 672-675.

Research output: Contribution to journal › Article › peer-review

Harvard

Pankova, AS, Cherepanova, ND, Golubev, P & Kuznetsov, MA 2019, 'Selective Synthesis of 2-Methylidenepyrrol-3-Ones from Diynones and Amines', Chemistry of Heterocyclic Compounds, vol. 55, no. 7, pp. 672-675. https://doi.org/10.1007/s10593-019-02515-4, https://doi.org/10.1007/s10593-019-02515-4

APA

Pankova, A. S., Cherepanova, N. D., Golubev, P., & Kuznetsov, M. A. (2019). Selective Synthesis of 2-Methylidenepyrrol-3-Ones from Diynones and Amines. Chemistry of Heterocyclic Compounds, 55(7), 672-675. https://doi.org/10.1007/s10593-019-02515-4, https://doi.org/10.1007/s10593-019-02515-4

Vancouver

Pankova AS, Cherepanova ND, Golubev P, Kuznetsov MA. Selective Synthesis of 2-Methylidenepyrrol-3-Ones from Diynones and Amines. Chemistry of Heterocyclic Compounds. 2019 Jul 15;55(7):672-675. https://doi.org/10.1007/s10593-019-02515-4, https://doi.org/10.1007/s10593-019-02515-4

Author

Pankova, Alena S. ; Cherepanova, Nadezhda D. ; Golubev, Pavel ; Kuznetsov, Mikhail A. / Selective Synthesis of 2-Methylidenepyrrol-3-Ones from Diynones and Amines. In: Chemistry of Heterocyclic Compounds. 2019 ; Vol. 55, No. 7. pp. 672-675.

BibTeX

@article{6041b35e7ae345aa8689bbc09b156c60,
title = "Selective Synthesis of 2-Methylidenepyrrol-3-Ones from Diynones and Amines",
abstract = "[Figure not available: see fulltext.] Addition of primary amines to 1-phenyl-5-trimethylsilylpenta-1,4-diyn-3-one with subsequent cyclization affords 5-phenyl-2-(trimethylsilylmethylidene)-1,2-dihydro-3H-pyrrol-3-ones. Both electron-rich and electron-deficient anilines and alkyl amines provide regio- and stereoselective formation of single product in high yields. The two-step transformation benefits from full atom economy, operational simplicity, and no need for additives and catalysts.",
keywords = "alkynes, diynones, enamines, pyrrolones, cyclization",
author = "Pankova, {Alena S.} and Cherepanova, {Nadezhda D.} and Pavel Golubev and Kuznetsov, {Mikhail A.}",
note = "статья",
year = "2019",
month = jul,
day = "15",
doi = "10.1007/s10593-019-02515-4",
language = "English",
volume = "55",
pages = "672--675",
journal = "Chemistry of Heterocyclic Compounds",
issn = "0009-3122",
publisher = "Springer Nature",
number = "7",

}

RIS

TY - JOUR

T1 - Selective Synthesis of 2-Methylidenepyrrol-3-Ones from Diynones and Amines

AU - Pankova, Alena S.

AU - Cherepanova, Nadezhda D.

AU - Golubev, Pavel

AU - Kuznetsov, Mikhail A.

N1 - статья

PY - 2019/7/15

Y1 - 2019/7/15

N2 - [Figure not available: see fulltext.] Addition of primary amines to 1-phenyl-5-trimethylsilylpenta-1,4-diyn-3-one with subsequent cyclization affords 5-phenyl-2-(trimethylsilylmethylidene)-1,2-dihydro-3H-pyrrol-3-ones. Both electron-rich and electron-deficient anilines and alkyl amines provide regio- and stereoselective formation of single product in high yields. The two-step transformation benefits from full atom economy, operational simplicity, and no need for additives and catalysts.

AB - [Figure not available: see fulltext.] Addition of primary amines to 1-phenyl-5-trimethylsilylpenta-1,4-diyn-3-one with subsequent cyclization affords 5-phenyl-2-(trimethylsilylmethylidene)-1,2-dihydro-3H-pyrrol-3-ones. Both electron-rich and electron-deficient anilines and alkyl amines provide regio- and stereoselective formation of single product in high yields. The two-step transformation benefits from full atom economy, operational simplicity, and no need for additives and catalysts.

KW - alkynes, diynones, enamines, pyrrolones, cyclization

UR - http://www.scopus.com/inward/record.url?scp=85070103496&partnerID=8YFLogxK

U2 - 10.1007/s10593-019-02515-4

DO - 10.1007/s10593-019-02515-4

M3 - Article

AN - SCOPUS:85070103496

VL - 55

SP - 672

EP - 675

JO - Chemistry of Heterocyclic Compounds

JF - Chemistry of Heterocyclic Compounds

SN - 0009-3122

IS - 7

ER -

ID: 61635151