Research output: Contribution to journal › Article › peer-review
[Figure not available: see fulltext.] Addition of primary amines to 1-phenyl-5-trimethylsilylpenta-1,4-diyn-3-one with subsequent cyclization affords 5-phenyl-2-(trimethylsilylmethylidene)-1,2-dihydro-3H-pyrrol-3-ones. Both electron-rich and electron-deficient anilines and alkyl amines provide regio- and stereoselective formation of single product in high yields. The two-step transformation benefits from full atom economy, operational simplicity, and no need for additives and catalysts.
Translated title of the contribution | Селективный синтез 2-метиленпиррол-3-онов из диинонов и аминов |
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Original language | English |
Pages (from-to) | 672-675 |
Number of pages | 4 |
Journal | Chemistry of Heterocyclic Compounds |
Volume | 55 |
Issue number | 7 |
DOIs | |
State | Published - 15 Jul 2019 |
ID: 61635151