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Rh2(esp)2-Catalyzed Coupling of α-Diazo-γ-butyrolactams with Aromatic Amines. / Zhukovsky, Daniil; Dar'in, Dmitry; Krasavin, Mikhail.

In: European Journal of Organic Chemistry, Vol. 2019, No. 27, 23.07.2019, p. 4377-4383.

Research output: Contribution to journal › Article › peer-review

Harvard

Zhukovsky, D, Dar'in, D & Krasavin, M 2019, 'Rh2(esp)2-Catalyzed Coupling of α-Diazo-γ-butyrolactams with Aromatic Amines', European Journal of Organic Chemistry, vol. 2019, no. 27, pp. 4377-4383. https://doi.org/10.1002/ejoc.201900565

APA

Zhukovsky, D., Dar'in, D., & Krasavin, M. (2019). Rh2(esp)2-Catalyzed Coupling of α-Diazo-γ-butyrolactams with Aromatic Amines. European Journal of Organic Chemistry, 2019(27), 4377-4383. https://doi.org/10.1002/ejoc.201900565

Vancouver

Zhukovsky D, Dar'in D, Krasavin M. Rh2(esp)2-Catalyzed Coupling of α-Diazo-γ-butyrolactams with Aromatic Amines. European Journal of Organic Chemistry. 2019 Jul 23;2019(27):4377-4383. https://doi.org/10.1002/ejoc.201900565

Author

Zhukovsky, Daniil ; Dar'in, Dmitry ; Krasavin, Mikhail. / Rh2(esp)2-Catalyzed Coupling of α-Diazo-γ-butyrolactams with Aromatic Amines. In: European Journal of Organic Chemistry. 2019 ; Vol. 2019, No. 27. pp. 4377-4383.

BibTeX

@article{4a6533f2ca474678b0767cc5094d2857,
title = "Rh2(esp)2-Catalyzed Coupling of α-Diazo-γ-butyrolactams with Aromatic Amines",
abstract = "Decomposition of α-diazo-γ-butyrolactams in the presence of aromatic and heteroaromatic amines, under Rh2(esp)2 catalysis, led to corresponding α-arylamino-γ-butyrolactams, which are of significant value for medicinal chemistry. The reaction scope encompasses primary as well as secondary, diversely substituted anilines and heteroaromatic amines. Insertion into the anilinic amino group was shown to be selective over amide and sulfonamide N–H insertion.",
keywords = "Amimnes, Homogeneous catalysis, Lactams, N–H insertion, ORGANIC-SYNTHESIS, DESIGN, N-H insertion, N-H BONDS, POTENT, CARBONIC-ANHYDRASE IX, CARBENE INSERTION, INHIBITORS, SELECTIVITY",
author = "Daniil Zhukovsky and Dmitry Dar'in and Mikhail Krasavin",
year = "2019",
month = jul,
day = "23",
doi = "10.1002/ejoc.201900565",
language = "English",
volume = "2019",
pages = "4377--4383",
journal = "European Journal of Organic Chemistry",
issn = "1434-193X",
publisher = "Wiley-Blackwell",
number = "27",

}

RIS

TY - JOUR

T1 - Rh2(esp)2-Catalyzed Coupling of α-Diazo-γ-butyrolactams with Aromatic Amines

AU - Zhukovsky, Daniil

AU - Dar'in, Dmitry

AU - Krasavin, Mikhail

PY - 2019/7/23

Y1 - 2019/7/23

N2 - Decomposition of α-diazo-γ-butyrolactams in the presence of aromatic and heteroaromatic amines, under Rh2(esp)2 catalysis, led to corresponding α-arylamino-γ-butyrolactams, which are of significant value for medicinal chemistry. The reaction scope encompasses primary as well as secondary, diversely substituted anilines and heteroaromatic amines. Insertion into the anilinic amino group was shown to be selective over amide and sulfonamide N–H insertion.

AB - Decomposition of α-diazo-γ-butyrolactams in the presence of aromatic and heteroaromatic amines, under Rh2(esp)2 catalysis, led to corresponding α-arylamino-γ-butyrolactams, which are of significant value for medicinal chemistry. The reaction scope encompasses primary as well as secondary, diversely substituted anilines and heteroaromatic amines. Insertion into the anilinic amino group was shown to be selective over amide and sulfonamide N–H insertion.

KW - Amimnes

KW - Homogeneous catalysis

KW - Lactams

KW - N–H insertion

KW - ORGANIC-SYNTHESIS

KW - DESIGN

KW - N-H insertion

KW - N-H BONDS

KW - POTENT

KW - CARBONIC-ANHYDRASE IX

KW - CARBENE INSERTION

KW - INHIBITORS

KW - SELECTIVITY

UR - http://www.scopus.com/inward/record.url?scp=85068082114&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/rh2esp2catalyzed-coupling-%CE%B1diazo%CE%B3butyrolactams-aromatic-amines

U2 - 10.1002/ejoc.201900565

DO - 10.1002/ejoc.201900565

M3 - Article

AN - SCOPUS:85068082114

VL - 2019

SP - 4377

EP - 4383

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

SN - 1434-193X

IS - 27

ER -

ID: 46204034