DOI

The reaction of 3-aryl-N-(aryl)propiolamides with arenes in TfOH at room temperature for 0.5 h led to 4,4-diaryl-3,4-dihydroquinolin-2-(1H)-ones in yields of 44-98%. The obtained dihydroquinolinones were further transformed into the corresponding N-acyl or N-formyl derivatives. For the latter, the superelectrophilic activation of the N-formyl group by TfOH in the reaction with benzene resulted in the formation of N-(diphenylmethyl)-substituted dihydroquinolinones.

Original languageEnglish
Pages (from-to)950-956
Number of pages7
JournalBeilstein Journal of Organic Chemistry
Volume12
DOIs
StatePublished - 11 May 2016

    Scopus subject areas

  • Organic Chemistry

    Research areas

  • Alkynes, Friedel-Crafts reactions, Quinolinones, Superacids, Superelectrophilic activation

ID: 7576360