Research output: Contribution to journal › Article › peer-review
Polyaromatic Hydrocarbon (PAH)-Based Aza-POPOPs: Synthesis, Photophysical Studies, and Nitroanalyte Sensing Abilities. / Mohammed, Mohammed S.; Kovalev, Igor S.; Slovesnova, Natalya V.; Sadieva, Leila K.; Platonov, Vadim A.; Novikov, Alexander S.; Santra, Sougata; Morozova, Julia E.; Zyryanov, Grigory V.; Charushin, Valery N.; Ranu, Brindaban C.
In: International Journal of Molecular Sciences, Vol. 24, No. 12, 10084, 13.06.2023.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Polyaromatic Hydrocarbon (PAH)-Based Aza-POPOPs: Synthesis, Photophysical Studies, and Nitroanalyte Sensing Abilities
AU - Mohammed, Mohammed S.
AU - Kovalev, Igor S.
AU - Slovesnova, Natalya V.
AU - Sadieva, Leila K.
AU - Platonov, Vadim A.
AU - Novikov, Alexander S.
AU - Santra, Sougata
AU - Morozova, Julia E.
AU - Zyryanov, Grigory V.
AU - Charushin, Valery N.
AU - Ranu, Brindaban C.
N1 - Mohammed, M.S.; Kovalev, I.S.; Slovesnova, N.V.; Sadieva, L.K.; Platonov, V.A.; Novikov, A.S.; Santra, S.; Morozova, J.E.; Zyryanov, G.V.; Charushin, V.N.; et al. Polyaromatic Hydrocarbon (PAH)-Based Aza-POPOPs: Synthesis, Photophysical Studies, and Nitroanalyte Sensing Abilities. Int. J. Mol. Sci. 2023, 24, 10084. https://doi.org/10.3390/ijms241210084
PY - 2023/6/13
Y1 - 2023/6/13
N2 - 1,4-Bis(5-phenyl-2-oxazolyl)benzene (POPOP) is a common scintillation fluorescent laser dye. In this manuscript, the synthesis of 2-Ar-5-(4-(4-Ar’-1H-1,2,3-triazol-1-yl)phenyl)-1,3,4-oxadiazoles (Ar, Ar’ = Ph, naphtalenyl-2, pyrenyl-1, triphenilenyl-2), as PAH-based aza-analogues of POPOP, by means of Cu-catalyzed click reaction between 2-(4-azidophenyl)-5-Ar-1,3,4-oxadiazole and terminal ethynyl-substituted PAHs is reported. An investigation of the photophysical properties of the obtained products was carried out, and their sensory response to nitroanalytes was evaluated. In the case of pyrenyl-1-substituted aza-POPOP, dramatic fluorescence quenching by nitroanalytes was observed.
AB - 1,4-Bis(5-phenyl-2-oxazolyl)benzene (POPOP) is a common scintillation fluorescent laser dye. In this manuscript, the synthesis of 2-Ar-5-(4-(4-Ar’-1H-1,2,3-triazol-1-yl)phenyl)-1,3,4-oxadiazoles (Ar, Ar’ = Ph, naphtalenyl-2, pyrenyl-1, triphenilenyl-2), as PAH-based aza-analogues of POPOP, by means of Cu-catalyzed click reaction between 2-(4-azidophenyl)-5-Ar-1,3,4-oxadiazole and terminal ethynyl-substituted PAHs is reported. An investigation of the photophysical properties of the obtained products was carried out, and their sensory response to nitroanalytes was evaluated. In the case of pyrenyl-1-substituted aza-POPOP, dramatic fluorescence quenching by nitroanalytes was observed.
KW - aza-POPOPs
KW - 1,4-bis(5-phenyl-2-oxazolyl)benzene analogues
KW - click reactions
KW - Photophysical studies
KW - fluorescence quenching
KW - nitro-explosives
KW - Chemosensors
KW - 1
KW - chemosensors
KW - photophysical studies
KW - 4-bis(5-phenyl-2-oxazolyl)benzene analogues
UR - https://www.mendeley.com/catalogue/2832f662-855d-3402-9eda-69cf7eecbfa0/
U2 - 10.3390/ijms241210084
DO - 10.3390/ijms241210084
M3 - Article
VL - 24
JO - International Journal of Molecular Sciences
JF - International Journal of Molecular Sciences
SN - 1422-0067
IS - 12
M1 - 10084
ER -
ID: 106484560