Research output: Contribution to journal › Article › peer-review
Polar BaCl(ClO4)·H2O layered chloride perchlorate. / Charkin, D. O.; Nazarchuk, E. V.; Stefanovich, S. Yu; Djangurazov, E. B.; Zadoya, A. I.; Siidra, O. I.
In: Inorganic Chemistry Communications, Vol. 84, 01.10.2017, p. 174-177.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Polar BaCl(ClO4)·H2O layered chloride perchlorate
AU - Charkin, D. O.
AU - Nazarchuk, E. V.
AU - Stefanovich, S. Yu
AU - Djangurazov, E. B.
AU - Zadoya, A. I.
AU - Siidra, O. I.
PY - 2017/10/1
Y1 - 2017/10/1
N2 - Synthesis and crystal structure of a polar layered chloride perchlorate, BaCl(ClO4)·H2O (1) where the chlorine atoms play two crystallographically different roles with ClVII centering the anionic [ClO4]− tetrahedra, and Cl− I centering the edge-sharing [ClBa4]7 + anion-centered tetrahedra is reported. SHG measurements confirm SHG activity of 1 as 5–6 SiO2 units. The polarity in the structure of 1 is resulted from the orientation of the perchlorate anions.
AB - Synthesis and crystal structure of a polar layered chloride perchlorate, BaCl(ClO4)·H2O (1) where the chlorine atoms play two crystallographically different roles with ClVII centering the anionic [ClO4]− tetrahedra, and Cl− I centering the edge-sharing [ClBa4]7 + anion-centered tetrahedra is reported. SHG measurements confirm SHG activity of 1 as 5–6 SiO2 units. The polarity in the structure of 1 is resulted from the orientation of the perchlorate anions.
KW - Anion-centered tetrahedra
KW - Chloride
KW - Perchlorate
KW - Polar compounds
KW - Single crystal X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=85028395661&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2017.08.022
DO - 10.1016/j.inoche.2017.08.022
M3 - Article
AN - SCOPUS:85028395661
VL - 84
SP - 174
EP - 177
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
ER -
ID: 9144571