Research output: Contribution to journal › Article › peer-review
Platinum(II) Complexes with 10-(Aryl)phenoxarsines : Synthesis, Cis/Trans Isomerization, and Luminescence. / Galimova, Milyausha F.; Begaliev, Temurbek A.; Zueva, Ekaterina M.; Kondrashova, Svetlana A.; Latypov, Shamil K.; Dobrynin, Alexey B.; Kolesnikov, Ilya E.; Musin, Rustem R.; Musina, Elvira I.; Karasik, Andrey A.
In: Inorganic Chemistry, Vol. 60, No. 9, 22.04.2021, p. 6804-6812.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Platinum(II) Complexes with 10-(Aryl)phenoxarsines
T2 - Synthesis, Cis/Trans Isomerization, and Luminescence
AU - Galimova, Milyausha F.
AU - Begaliev, Temurbek A.
AU - Zueva, Ekaterina M.
AU - Kondrashova, Svetlana A.
AU - Latypov, Shamil K.
AU - Dobrynin, Alexey B.
AU - Kolesnikov, Ilya E.
AU - Musin, Rustem R.
AU - Musina, Elvira I.
AU - Karasik, Andrey A.
N1 - Publisher Copyright: ©
PY - 2021/4/22
Y1 - 2021/4/22
N2 - Synthesis and structural and photophysical characterization of platinum dihalogenide complexes formulated as [PtHal2L2], where Hal = Cl and I, with different 10-(aryl)phenoxarsine ligands such as 10-(p-chlorophenyl)phenoxarsine, 10-(p-tolyl)phenoxarsine, and 10-(phenyl)phenoxarsine are reported. The structures of complexes were determined by NMR spectroscopy, mass spectrometry, and X-ray analysis. Cis/trans isomerism of the complexes in solution was studied by NMR spectroscopy. In the solid state, under UV irradiation, platinum diiodide trans complexes exhibit an intense orange-red emission, which was attributed to a metal halide-centered triplet state. The UV/vis absorption and emission properties were studied and rationalized by density functional theory (DFT) and time-dependent DFT calculations.
AB - Synthesis and structural and photophysical characterization of platinum dihalogenide complexes formulated as [PtHal2L2], where Hal = Cl and I, with different 10-(aryl)phenoxarsine ligands such as 10-(p-chlorophenyl)phenoxarsine, 10-(p-tolyl)phenoxarsine, and 10-(phenyl)phenoxarsine are reported. The structures of complexes were determined by NMR spectroscopy, mass spectrometry, and X-ray analysis. Cis/trans isomerism of the complexes in solution was studied by NMR spectroscopy. In the solid state, under UV irradiation, platinum diiodide trans complexes exhibit an intense orange-red emission, which was attributed to a metal halide-centered triplet state. The UV/vis absorption and emission properties were studied and rationalized by density functional theory (DFT) and time-dependent DFT calculations.
UR - http://www.scopus.com/inward/record.url?scp=85106069950&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.1c00672
DO - 10.1021/acs.inorgchem.1c00672
M3 - Article
C2 - 33886298
AN - SCOPUS:85106069950
VL - 60
SP - 6804
EP - 6812
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 9
ER -
ID: 86366390