TY - JOUR

T1 - Orbital collapse and dual states of the 5g electrons in superheavy elements

AU - Tupitsyn, I. I.

AU - Savelyev, I. M.

AU - Kozhedub, Y. S.

AU - Telnov, D. A.

AU - Dulaev, N. K.

AU - Malyshev, A. V.

AU - Prokhorchuk, E. A.

AU - Shabaev, V. M.

PY - 2024/4/5

Y1 - 2024/4/5

N2 - The problem of orbital collapse of the $5g$ and $6f$ electrons in atoms of superheavy elements (SHE) is considered. Previously, the presence of the orbital collapse was established for the $4f$ and $5f$ elements of the periodic table. Because of the large centrifugal term for the $f$ and $g$ electrons, the effective radial potential has two wells, one narrow and deep and the other wide but shallow. Depending on the external parameters, the electron can be either localized in the outer well with low binding energy and large average radius or in the inner one with higher energy and smaller radius. In this work, we demonstrate the existence of the orbital collapse for the $5g$ electrons when changing the total angular momentum $J$ of the atom. We also found that for some SHE elements, two different solutions of the same Dirac-Fock equations may coexist, with the $5g$ electron localized either in the inner or outer well. In both cases, the radial wave functions are nodeless. The problem of the dual-state coexistence is studied by the configuration-interaction method in the Dirac-Fock-Sturm orbital basis as well.

AB - The problem of orbital collapse of the $5g$ and $6f$ electrons in atoms of superheavy elements (SHE) is considered. Previously, the presence of the orbital collapse was established for the $4f$ and $5f$ elements of the periodic table. Because of the large centrifugal term for the $f$ and $g$ electrons, the effective radial potential has two wells, one narrow and deep and the other wide but shallow. Depending on the external parameters, the electron can be either localized in the outer well with low binding energy and large average radius or in the inner one with higher energy and smaller radius. In this work, we demonstrate the existence of the orbital collapse for the $5g$ electrons when changing the total angular momentum $J$ of the atom. We also found that for some SHE elements, two different solutions of the same Dirac-Fock equations may coexist, with the $5g$ electron localized either in the inner or outer well. In both cases, the radial wave functions are nodeless. The problem of the dual-state coexistence is studied by the configuration-interaction method in the Dirac-Fock-Sturm orbital basis as well.

UR - http://arxiv.org/abs/2402.02609

UR - https://www.mendeley.com/catalogue/253b614d-9ea4-3200-bd08-ba751011c154/

U2 - 10.1103/physreva.109.042807

DO - 10.1103/physreva.109.042807

M3 - Article

VL - 109

JO - Physical Review A - Atomic, Molecular, and Optical Physics

JF - Physical Review A - Atomic, Molecular, and Optical Physics

SN - 1050-2947

IS - 4

M1 - 042807

ER -