Research output: Contribution to journal › Article › peer-review
Nucleophilic addition of aromatic amide oximes to [2-B10H9NCC2H5]– anion. / Bolotin, D. S.; Demakova, M. Ya; Daines, E. A.; Avdontseva, M. S.; Zhdanov, A. P.; Zhizhin, K. Yu; Kuznetsov, N. T.
In: Russian Journal of General Chemistry, Vol. 87, No. 1, 01.01.2017, p. 37-43.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Nucleophilic addition of aromatic amide oximes to [2-B10H9NCC2H5]– anion
AU - Bolotin, D. S.
AU - Demakova, M. Ya
AU - Daines, E. A.
AU - Avdontseva, M. S.
AU - Zhdanov, A. P.
AU - Zhizhin, K. Yu
AU - Kuznetsov, N. T.
PY - 2017/1/1
Y1 - 2017/1/1
N2 - A series of closo-decaborate anions containing an O-iminoacylamide oxime fragment were synthesized by nucleophilic addition of aromatic amide oximes to 2-propionitrilium closo-decaborate anion. The isolated compounds were characterized by IR, 1H, 13C–{1H}, and 11B–{1H} NMR, and mass spectra. The structure of (Ph4P)[2-B10H9NH=C(Et)ON=C(NH2)C6H4Me-2] was determined by single-crystal X-ray analysis.
AB - A series of closo-decaborate anions containing an O-iminoacylamide oxime fragment were synthesized by nucleophilic addition of aromatic amide oximes to 2-propionitrilium closo-decaborate anion. The isolated compounds were characterized by IR, 1H, 13C–{1H}, and 11B–{1H} NMR, and mass spectra. The structure of (Ph4P)[2-B10H9NH=C(Et)ON=C(NH2)C6H4Me-2] was determined by single-crystal X-ray analysis.
KW - amide oximes
KW - closo-decaborate anion
KW - nitrilium derivatives
KW - nucleophilic addition
KW - oximes
UR - http://www.scopus.com/inward/record.url?scp=85021758292&partnerID=8YFLogxK
U2 - 10.1134/S107036321701008X
DO - 10.1134/S107036321701008X
M3 - Article
AN - SCOPUS:85021758292
VL - 87
SP - 37
EP - 43
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 1
ER -
ID: 9169775