A series of closo-decaborate anions containing an O-iminoacylamide oxime fragment were synthesized by nucleophilic addition of aromatic amide oximes to 2-propionitrilium closo-decaborate anion. The isolated compounds were characterized by IR, 1H, 13C–{1H}, and 11B–{1H} NMR, and mass spectra. The structure of (Ph4P)[2-B10H9NH=C(Et)ON=C(NH2)C6H4Me-2] was determined by single-crystal X-ray analysis.

Original languageEnglish
Pages (from-to)37-43
Number of pages7
JournalRussian Journal of General Chemistry
Volume87
Issue number1
DOIs
StatePublished - 1 Jan 2017

    Research areas

  • amide oximes, closo-decaborate anion, nitrilium derivatives, nucleophilic addition, oximes

    Scopus subject areas

  • Chemistry(all)

ID: 9169775