Nitrate-selective solid contact electrodes with poly(3-octylthiophene) and poly(aniline) as ion-to-electron transducers buffered with electron-ion- exchanging resin

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Nitrate-selective solid contact electrodes with poly(3-octylthiophene) and poly(aniline) as ion-to-electron transducers buffered with electron-ion- exchanging resin. / Khripoun, Galina A.; Volkova, Elina A.; Liseenkov, Artiom V.; Mikhelson, Konstantin N.

In: Electroanalysis, Vol. 18, No. 13-14, 07.2006, p. 1322-1328.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{e6cd02f2d64e470f857c99c45f4d2580,

title = "Nitrate-selective solid contact electrodes with poly(3-octylthiophene) and poly(aniline) as ion-to-electron transducers buffered with electron-ion- exchanging resin",

abstract = "The study of nitrate selective solid contact electrodes containing poly(3-octyl)thiophene and poly(aniline) demonstrated the advantage of buffering the transducing layer with electron-ion-exchanging resin. The buffering, in particular in the case of poly(aniline) doped with nitrate anions ensured significant improvement of the long-term stability and piece-to-piece reproducibility of the electrode potentials. It is shown that the redox species causes potential drift after a long time delay, probably because of slow diffusion in the membrane bulk.",

keywords = "Electron-ion-exchanging resin, Ion-selective electrodes, Nitrate, Poly(3-octylthiophene), Poly(aniline), Solid contact, Solvent-polymeric membranes",

author = "Khripoun, {Galina A.} and Volkova, {Elina A.} and Liseenkov, {Artiom V.} and Mikhelson, {Konstantin N.}",

year = "2006",

month = jul,

doi = "10.1002/elan.200603532",

language = "English",

volume = "18",

pages = "1322--1328",

journal = "Electroanalysis",

issn = "1040-0397",

publisher = "Wiley-Blackwell",

number = "13-14",

}

RIS

TY - JOUR

T1 - Nitrate-selective solid contact electrodes with poly(3-octylthiophene) and poly(aniline) as ion-to-electron transducers buffered with electron-ion- exchanging resin

AU - Khripoun, Galina A.

AU - Volkova, Elina A.

AU - Liseenkov, Artiom V.

AU - Mikhelson, Konstantin N.

PY - 2006/7

Y1 - 2006/7

N2 - The study of nitrate selective solid contact electrodes containing poly(3-octyl)thiophene and poly(aniline) demonstrated the advantage of buffering the transducing layer with electron-ion-exchanging resin. The buffering, in particular in the case of poly(aniline) doped with nitrate anions ensured significant improvement of the long-term stability and piece-to-piece reproducibility of the electrode potentials. It is shown that the redox species causes potential drift after a long time delay, probably because of slow diffusion in the membrane bulk.

AB - The study of nitrate selective solid contact electrodes containing poly(3-octyl)thiophene and poly(aniline) demonstrated the advantage of buffering the transducing layer with electron-ion-exchanging resin. The buffering, in particular in the case of poly(aniline) doped with nitrate anions ensured significant improvement of the long-term stability and piece-to-piece reproducibility of the electrode potentials. It is shown that the redox species causes potential drift after a long time delay, probably because of slow diffusion in the membrane bulk.

KW - Electron-ion-exchanging resin

KW - Ion-selective electrodes

KW - Nitrate

KW - Poly(3-octylthiophene)

KW - Poly(aniline)

KW - Solid contact

KW - Solvent-polymeric membranes

UR - http://www.scopus.com/inward/record.url?scp=33746597938&partnerID=8YFLogxK

U2 - 10.1002/elan.200603532

DO - 10.1002/elan.200603532

M3 - Article

AN - SCOPUS:33746597938

VL - 18

SP - 1322

EP - 1328

JO - Electroanalysis

JF - Electroanalysis

SN - 1040-0397

IS - 13-14

ER -

ID: 92358694