Nickel(I) complex as the final product of the sequence of spontaneous transformations in the system Ni(Allyl) 2-(2,6-diisopropylphenyl) diazabutadiene

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Nickel(I) complex as the final product of the sequence of spontaneous transformations in the system Ni(Allyl) ₂-(2,6-diisopropylphenyl) diazabutadiene. / Kraikivskii, P. B.; Saraev, V. V.; Bocharova, V. V.; Romanenko, G. V.; Matveev, D. A.; Petrovskii, S. K.; Kuzakov, A. S.

In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Vol. 38, No. 6, 01.06.2012, p. 416-425.

Research output: Contribution to journal › Article › peer-review

Author

Kraikivskii, P. B. ; Saraev, V. V. ; Bocharova, V. V. ; Romanenko, G. V. ; Matveev, D. A. ; Petrovskii, S. K. ; Kuzakov, A. S. / Nickel(I) complex as the final product of the sequence of spontaneous transformations in the system Ni(Allyl) ₂-(2,6-diisopropylphenyl) diazabutadiene. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2012 ; Vol. 38, No. 6. pp. 416-425.

BibTeX

@article{397c5d0da4d94d1486682591f633c785,

title = "Nickel(I) complex as the final product of the sequence of spontaneous transformations in the system Ni(Allyl) 2-(2,6-diisopropylphenyl) diazabutadiene",

abstract = "A reaction of Ni(Allyl) 2 with bis(2,6-diisopropylphenyl) diazabutadiene gave an imino amide allyl nickel(II) complex (I). Complicated rearrangements of the imino amide ligand in the coordination sphere of complex I spontaneously yielded a paramagnetic Ni(I) π-allyl complex as a final reaction product. The nickel complexes produced in this system were studied by EPR, IR, and 2D NMR spectroscopy and mass spectrometry. Structure I was examined by X-ray diffraction.",

author = "Kraikivskii, {P. B.} and Saraev, {V. V.} and Bocharova, {V. V.} and Romanenko, {G. V.} and Matveev, {D. A.} and Petrovskii, {S. K.} and Kuzakov, {A. S.}",

year = "2012",

month = jun,

day = "1",

doi = "10.1134/S1070328412050053",

language = "English",

volume = "38",

pages = "416--425",

journal = "Russian Journal of Coordination Chemistry",

issn = "1070-3284",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "6",

}

RIS

TY - JOUR

T1 - Nickel(I) complex as the final product of the sequence of spontaneous transformations in the system Ni(Allyl) 2-(2,6-diisopropylphenyl) diazabutadiene

AU - Kraikivskii, P. B.

AU - Saraev, V. V.

AU - Bocharova, V. V.

AU - Romanenko, G. V.

AU - Matveev, D. A.

AU - Petrovskii, S. K.

AU - Kuzakov, A. S.

PY - 2012/6/1

Y1 - 2012/6/1

N2 - A reaction of Ni(Allyl) 2 with bis(2,6-diisopropylphenyl) diazabutadiene gave an imino amide allyl nickel(II) complex (I). Complicated rearrangements of the imino amide ligand in the coordination sphere of complex I spontaneously yielded a paramagnetic Ni(I) π-allyl complex as a final reaction product. The nickel complexes produced in this system were studied by EPR, IR, and 2D NMR spectroscopy and mass spectrometry. Structure I was examined by X-ray diffraction.

AB - A reaction of Ni(Allyl) 2 with bis(2,6-diisopropylphenyl) diazabutadiene gave an imino amide allyl nickel(II) complex (I). Complicated rearrangements of the imino amide ligand in the coordination sphere of complex I spontaneously yielded a paramagnetic Ni(I) π-allyl complex as a final reaction product. The nickel complexes produced in this system were studied by EPR, IR, and 2D NMR spectroscopy and mass spectrometry. Structure I was examined by X-ray diffraction.

UR - http://www.scopus.com/inward/record.url?scp=84864618458&partnerID=8YFLogxK

U2 - 10.1134/S1070328412050053

DO - 10.1134/S1070328412050053

M3 - Article

AN - SCOPUS:84864618458

VL - 38

SP - 416

EP - 425

JO - Russian Journal of Coordination Chemistry

JF - Russian Journal of Coordination Chemistry

SN - 1070-3284

IS - 6

ER -

ID: 51891292