Research output: Contribution to journal › Article › peer-review
A reaction of Ni(Allyl) 2 with bis(2,6-diisopropylphenyl) diazabutadiene gave an imino amide allyl nickel(II) complex (I). Complicated rearrangements of the imino amide ligand in the coordination sphere of complex I spontaneously yielded a paramagnetic Ni(I) π-allyl complex as a final reaction product. The nickel complexes produced in this system were studied by EPR, IR, and 2D NMR spectroscopy and mass spectrometry. Structure I was examined by X-ray diffraction.
| Original language | English |
|---|---|
| Pages (from-to) | 416-425 |
| Number of pages | 10 |
| Journal | Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
| Volume | 38 |
| Issue number | 6 |
| DOIs | |
| State | Published - 1 Jun 2012 |
ID: 51891292