DOI

Reaction between [BiBr6]3− and Br2 in HBr in presence of trimethylammonium bromide results in self-assembly of a supramolecular halometalate-polybromide derivative (Me3NH)3{[Bi2Br9](Br2)} belonging to a novel structural type. DFT calculations allowed estimation of Br⋯Br contact energies (1.3–4.4 kcal/mol).

Original languageEnglish
Pages (from-to)169-173
Number of pages5
JournalInorganic Chemistry Communications
Volume98
DOIs
StatePublished - 1 Dec 2018

    Scopus subject areas

  • Materials Chemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

    Research areas

  • Bismuth, Halogen bonding, Polybromides, QTAIM, Supramolecular contacts, ANIONS, HYDROGEN, BROMINE, COMPLEXES, CHEMISTRY, NETWORKS, LIQUID-BASED SYNTHESIS

ID: 36064117