Mononuclear Zn(II) 3,5-Diiodosalicylate Complex with 3-Chloropyridine

Mononuclear Zn(II) 3,5-Diiodosalicylate Complex with 3-Chloropyridine: Synthesis and Features of Non-Covalent Interactions in the Solid State

Research output: Contribution to journal › Article › peer-review

Institute of Chemistry

DOI

https://doi.org/10.1134/s0036023621060061
Final published version

M. A. Bondarenko
A. S. Novikov
S. A. Adonin

The reaction of zinc(II) nitrate with 3,5-diiodosalicylic acid in the presence of 3-chloropyridine gave the heteroligand complex [(3-ClPy)(2)ZnDISA(2)] (1), which was studied by X-ray diffraction. The crystal structure of 1 includes non-covalent I center dot center dot center dot O interactions (halogen bonds), the energies of which were estimated by quantum chemical calculations.

Original language	English
Pages (from-to)	814-819
Number of pages	6
Journal	Russian Journal of Inorganic Chemistry
Volume	66
Issue number	6
DOIs	https://doi.org/10.1134/s0036023621060061
State	Published - 1 Jun 2021

Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)

Research areas

crystal structure, halogen bond, N-donor ligands, quantum chemical calculations, zinc complexes, ANIONS, VAN, SUBSTITUENTS, NICKEL(II), LUMINESCENT, RADII, COORDINATION POLYMERS, METAL-IONS

ID: 85773298