Research output: Contribution to journal › Article › peer-review
Modification of hydrophobic sorbents by cobalt chloride in order to concentrate low molecular polar organic substances from the air for subsequent gas chromatographic determination. / Rodinkov, O. V.; Zhuravleva, G. A.; Bugaichenko, A. S.; Viktorova, M. I.; Postnov, V. N.; Novikov, A. G.
In: Talanta, Vol. 144, 15569, 01.11.2015, p. 427-431.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Modification of hydrophobic sorbents by cobalt chloride in order to concentrate low molecular polar organic substances from the air for subsequent gas chromatographic determination
AU - Rodinkov, O. V.
AU - Zhuravleva, G. A.
AU - Bugaichenko, A. S.
AU - Viktorova, M. I.
AU - Postnov, V. N.
AU - Novikov, A. G.
PY - 2015/11/1
Y1 - 2015/11/1
N2 - Abstract The article presents a new method of modification of hydrophobic sorbents. To improve sorption pre-concentration of polar organic compounds in the air analysis, these sorbents are coated with cobalt chloride. This modification increases retention volume of lower alcohols by 5-10 fold as compared to that of unmodified sorbents and solves the problem of gas-chromatographic determination at 1-2 ppb (micrograms/m3) by using the most common flame ionization detector. It should be noted that the modification of hydrophobic sorbents by cobalt chloride has little influence on their porosimetry parameters (specific surface area, proportions of meso- and micropores) and modified sorbents are capable of retaining hydrophobic nonpolar and weakly polar analytes as well as original unmodified sorbents. Thus, a fairly simple procedure leads to a large positive effect.
AB - Abstract The article presents a new method of modification of hydrophobic sorbents. To improve sorption pre-concentration of polar organic compounds in the air analysis, these sorbents are coated with cobalt chloride. This modification increases retention volume of lower alcohols by 5-10 fold as compared to that of unmodified sorbents and solves the problem of gas-chromatographic determination at 1-2 ppb (micrograms/m3) by using the most common flame ionization detector. It should be noted that the modification of hydrophobic sorbents by cobalt chloride has little influence on their porosimetry parameters (specific surface area, proportions of meso- and micropores) and modified sorbents are capable of retaining hydrophobic nonpolar and weakly polar analytes as well as original unmodified sorbents. Thus, a fairly simple procedure leads to a large positive effect.
KW - Air analysis
KW - Cobalt chloride
KW - Pre-concentration
KW - Sorbents
KW - Surface-layer polytetrafluoroethylene (PTFE)
KW - Volatile organic compounds
UR - http://www.scopus.com/inward/record.url?scp=84936858008&partnerID=8YFLogxK
U2 - 10.1016/j.talanta.2015.04.069
DO - 10.1016/j.talanta.2015.04.069
M3 - Article
VL - 144
SP - 427
EP - 431
JO - Talanta
JF - Talanta
SN - 0039-9140
M1 - 15569
ER -
ID: 3944709