Standard

Mechanochemical Approach for Amidoxime Synthesis. / Байкова, Светлана Олеговна; Солодянкина, Ольга Владимировна; Байков, Сергей Валентинович; Кыльчик, Алёна; Игнатов, Евгений Владиславович; Крюкова, Софья Сергеевна; Исламова, Регина Маратовна; Боярский, Вадим Павлович.

In: Asian Journal of Organic Chemistry, Vol. 15, No. 2, e70331, 16.02.2026.

Research output: Contribution to journal › Article › peer-review

Harvard

Байкова, СО, Солодянкина, ОВ, Байков, СВ, Кыльчик, А, Игнатов, ЕВ, Крюкова, СС, Исламова, РМ & Боярский, ВП 2026, 'Mechanochemical Approach for Amidoxime Synthesis', Asian Journal of Organic Chemistry, vol. 15, no. 2, e70331. https://doi.org/10.1002/ajoc.70331

APA

Байкова, С. О., Солодянкина, О. В., Байков, С. В., Кыльчик, А., Игнатов, Е. В., Крюкова, С. С., Исламова, Р. М., & Боярский, В. П. (2026). Mechanochemical Approach for Amidoxime Synthesis. Asian Journal of Organic Chemistry, 15(2), [e70331]. https://doi.org/10.1002/ajoc.70331

Vancouver

Байкова СО, Солодянкина ОВ, Байков СВ, Кыльчик А, Игнатов ЕВ, Крюкова СС et al. Mechanochemical Approach for Amidoxime Synthesis. Asian Journal of Organic Chemistry. 2026 Feb 16;15(2). e70331. https://doi.org/10.1002/ajoc.70331

Author

Байкова, Светлана Олеговна ; Солодянкина, Ольга Владимировна ; Байков, Сергей Валентинович ; Кыльчик, Алёна ; Игнатов, Евгений Владиславович ; Крюкова, Софья Сергеевна ; Исламова, Регина Маратовна ; Боярский, Вадим Павлович. / Mechanochemical Approach for Amidoxime Synthesis. In: Asian Journal of Organic Chemistry. 2026 ; Vol. 15, No. 2.

BibTeX

@article{37b2b619fb724cf5a217cd290c457114,
title = "Mechanochemical Approach for Amidoxime Synthesis",
abstract = "We have developed a convenient and modern method for obtaining amidoximes from aryl‐ or heteroaryl nitriles and hydroxylamine hydrochloride in the presence of a base using mechanochemical activation of the starting compounds. The method does not require the use of large volumes of solvents; the reaction occurs at room temperature for 2 h and provides high isolated yields of the corresponding amidoximes for most of the nitriles studied. We were also the first to use a mechanochemical approach to modify polysiloxanes. We demonstrated the possibility of synthesizing a functionalized copolysiloxane containing amidoxime functions and showed that the use of mechanochemical activation allows one to overcome one of the fundamental difficulties encountered by synthetics in the functionalization of polysiloxanes—reaction heterogeneity.",
author = "Байкова, {Светлана Олеговна} and Солодянкина, {Ольга Владимировна} and Байков, {Сергей Валентинович} and Алёна Кыльчик and Игнатов, {Евгений Владиславович} and Крюкова, {Софья Сергеевна} and Исламова, {Регина Маратовна} and Боярский, {Вадим Павлович}",
year = "2026",
month = feb,
day = "16",
doi = "10.1002/ajoc.70331",
language = "English",
volume = "15",
journal = "Asian Journal of Organic Chemistry",
issn = "2193-5807",
publisher = "Wiley-Blackwell",
number = "2",

}

RIS

TY - JOUR

T1 - Mechanochemical Approach for Amidoxime Synthesis

AU - Байкова, Светлана Олеговна

AU - Солодянкина, Ольга Владимировна

AU - Байков, Сергей Валентинович

AU - Кыльчик, Алёна

AU - Игнатов, Евгений Владиславович

AU - Крюкова, Софья Сергеевна

AU - Исламова, Регина Маратовна

AU - Боярский, Вадим Павлович

PY - 2026/2/16

Y1 - 2026/2/16

N2 - We have developed a convenient and modern method for obtaining amidoximes from aryl‐ or heteroaryl nitriles and hydroxylamine hydrochloride in the presence of a base using mechanochemical activation of the starting compounds. The method does not require the use of large volumes of solvents; the reaction occurs at room temperature for 2 h and provides high isolated yields of the corresponding amidoximes for most of the nitriles studied. We were also the first to use a mechanochemical approach to modify polysiloxanes. We demonstrated the possibility of synthesizing a functionalized copolysiloxane containing amidoxime functions and showed that the use of mechanochemical activation allows one to overcome one of the fundamental difficulties encountered by synthetics in the functionalization of polysiloxanes—reaction heterogeneity.

AB - We have developed a convenient and modern method for obtaining amidoximes from aryl‐ or heteroaryl nitriles and hydroxylamine hydrochloride in the presence of a base using mechanochemical activation of the starting compounds. The method does not require the use of large volumes of solvents; the reaction occurs at room temperature for 2 h and provides high isolated yields of the corresponding amidoximes for most of the nitriles studied. We were also the first to use a mechanochemical approach to modify polysiloxanes. We demonstrated the possibility of synthesizing a functionalized copolysiloxane containing amidoxime functions and showed that the use of mechanochemical activation allows one to overcome one of the fundamental difficulties encountered by synthetics in the functionalization of polysiloxanes—reaction heterogeneity.

UR - https://aces.onlinelibrary.wiley.com/doi/10.1002/ajoc.70331

UR - https://www.mendeley.com/catalogue/d97516a0-7dbd-323a-a2f5-c2e71aab7d42/

U2 - 10.1002/ajoc.70331

DO - 10.1002/ajoc.70331

M3 - Article

VL - 15

JO - Asian Journal of Organic Chemistry

JF - Asian Journal of Organic Chemistry

SN - 2193-5807

IS - 2

M1 - e70331

ER -

ID: 148846071